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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
GLP compliance:
not specified
Type of method:
effusion method: Knudsen cell
Specific details on test material used for the study:
Batch no.: #210162718
Composition: Reaction products of linseed-oil fatty acids, 4,4'-methylendiphenyldiglycidylether with neodecanoic fatty acid, oxiranylmethylester
Purity: 100 % as per definition of UVCB
Key result
Temp.:
20 °C
Vapour pressure:
0.001 Pa
Remarks on result:
other: calculated from the regression equation
Key result
Temp.:
25 °C
Vapour pressure:
0.002 Pa
Remarks on result:
other: calculated from the regression equation
Temp.:
30 °C
Vapour pressure:
0.002 Pa
Temp.:
45 °C
Vapour pressure:
0.005 Pa
Temp.:
60 °C
Vapour pressure:
0.011 Pa

- The measured values for temperature and vapour pressure were evaluated as follows:

 Parameter  T 1/T   log P
 Unit  K Pa 1/K  log Pa
 Value  303.2 2.43E-03  3.2982E-03  -2.6144
 Value  318.2 5.43E-03  3.1427E-03  -2.2653
 Value  333.2 1.11E-02  3.0012E-03  -1.9555

T: Temperature (K) = 273.15 + t (°C)

- For the test substance, the following vapour pressures at 20 °C and at 25 °C were calculated from the regression equation:

Vapour pressure at 20 °C: 1.37E-03 Pa

Vapour pressure at 25 °C: 1.83E-03 Pa

Conclusions:
Under the study conditions, the vapour pressure of the test substance was determined to be 1.37E-03 and 1.83E-03 Pa at 20 and 25°C, respectively.
Executive summary:

A study was conducted to determine the vapour pressure of the test substance according to OECD Guideline 104 and EU Method A.4. The vapour pressure of the test substance was determined by the Knudsen cell effusion method. The test substance was weighed into the 4 Knudsen cells, which were set into vacuum chamber at 10-05 Pa or lower followed by measurements at 30, 45, 60 and 75 °C. The test substance colour became darker at 75 °C, hence the measurements at this temperature were not used for calculations. The measured values for temperature and vapour pressure were evaluated as follows: 2.43E-03, 5.43E-03 and 1.11E-02 at 30, 45, and 60°C, respectively. Under the study conditions, the vapour pressures of the test substance were determined (by calculation) to be 1.37E-03 and 1.83E-03 Pa at 20 and 25°C, respectively (Henke, 2016).

Description of key information

The vapour pressure was determined according to OECD Guideline 104 and EU Method A.4 (effusion method: Knudsen cell) (Henke, 2016).

Key value for chemical safety assessment

Vapour pressure:
0.011 Pa
at the temperature of:
60 °C

Additional information