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Diss Factsheets

Environmental fate & pathways

Adsorption / desorption

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Administrative data

Link to relevant study record(s)

Description of key information

The adsorption coefficient log Koc was determined to be 3.8 for soil and 4.0 for sewage sludge.

Key value for chemical safety assessment

Koc at 20 °C:
10 000

Additional information

A study was conducted to determine the adsorption coefficient (Koc) on soil and sewage sludge of the read across substance ‘structural analogue 2’ using high performance liquid chromatography (HPLC) according to OECD Guideline 121 and EU Method C.19. The test was performed at a controlled temperature (22.7 °C, mean value) with a mobile phase consisting of 50 % acetonitrile and 50 % HPLC water. A 50 mg/L test substance sample was analysed threefold via HPLC on a cyanopropyl (CN-) column with DADdetection. Calibrations were performed using eight reference items for soil and seven for sewage sludge with known log Koc values (given by the guidelines). The reference items were measured twice, once before and once after the measurement (double injection of one replicate) of the test item. Void time of the HPLC-system was determined with sodium nitrate. Two individual log Koc values for soil and for sewage sludge for the test item were derived under consideration of the first and second calibration. Finally, a mean value for soil and for sewage sludge was calculated from these individual log Koc values. Based on these data, log Koc values of 3.8 for soil and 4.0 for sewage sludge were determined (Goller, 2015).

[LogKoc: 4.0]