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Diss Factsheets

Physical & Chemical properties

Flash point

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2013-10-28
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions
Remarks:
The study was conducted according to an appropriate test method and under the quality standard of ISO 9001:2008.
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Qualifier:
according to guideline
Guideline:
ISO 2719 (Determination of flash point - Pensky-Martens closed cup method)
Version / remarks:
2002
GLP compliance:
no
Other quality assurance:
other: ISO 9001:2008
Type of method:
non-equilibrium method closed cup
Flash point apparatus:
Pensky-Martens apparatus
Key result
Flash point:
111 °C
Atm. press.:
1 013 hPa

Test

Measured value [°C]

Corrected value [°C]

Preliminary test

 

 

1

109.1

110.4

2

110.1

111.4

 

Mean value*

111 °C

*The mean value is calculated from test 1 and 2 and rounded to ± 0.5 °C.

Interpretation of results:
GHS criteria not met
Conclusions:
A flash point value of 111°C at 1013 hPa was determined for the substance using a relevant test method and in compliance with a known quality system (ISO 9001:2008). The result is considered to be reliable.

Description of key information

Flash point 111°C at 1013 hPa (ISO 2719)

Key value for chemical safety assessment

Flash point at 101 325 Pa:
111 °C

Additional information

Two reliable measured flash point studies are available for the substance from the same author (Haas 2014), conducted in compliance with a known quality system (ISO 9001:2008). A flash point value of 111°C at 1013 hPa was determined for the substance using a closed-cup method in accordance with ISO Test Method 2719. Similarly, a limit flash point value of >110°C at 1013 hPa was determined for the substance using a rapid equilibrium closed-cup method in accordance with ISO Test Method 3679. The non-equilibrium closed-cup method is selected as key study because it is not a limit value.

A measured flash point of 111°C at 1013 hPa and measured boiling point of 246.1°C at 1013 hPa indicate that the substance should not be classified for flammability in accordance with Regulation (EC) No. 1272/2008.