Registration Dossier
Registration Dossier
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EC number: 204-514-8 | CAS number: 122-00-9
Guidance on Safe Use
Guidance on Safe Use
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Administrative data
First-aid measures
Inhalation: Move exposed person to fresh air. Keep person warm and at rest. If
not breathing, if breathing is irregular or if respiratory arrest occurs,
provide artificial respiration or oxygen by trained personnel. It may
be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Get medical attention if adverse health effects persist
or are severe. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Ingestion: Wash out mouth with water. Move exposed person to fresh air.
Keep person warm and at rest. If material has been swallowed and
the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be
dangerous. Do not induce vomiting unless directed to do so by
medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Get medical attention. Never
give anything by mouth to an unconscious person. If unconscious,
place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact: Flush contaminated skin with plenty of water. Remove contaminated
clothing and shoes. Get medical attention if symptoms occur. Wash
clothing before reuse. Clean shoes thoroughly before reuse.
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.
not breathing, if breathing is irregular or if respiratory arrest occurs,
provide artificial respiration or oxygen by trained personnel. It may
be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Get medical attention if adverse health effects persist
or are severe. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Ingestion: Wash out mouth with water. Move exposed person to fresh air.
Keep person warm and at rest. If material has been swallowed and
the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be
dangerous. Do not induce vomiting unless directed to do so by
medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Get medical attention. Never
give anything by mouth to an unconscious person. If unconscious,
place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact: Flush contaminated skin with plenty of water. Remove contaminated
clothing and shoes. Get medical attention if symptoms occur. Wash
clothing before reuse. Clean shoes thoroughly before reuse.
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: In case of fire, use water spray (fog), foam, dry chemical or CO2.
Unsuitable extinguishing media: None known.
Special hazards arising from the substance or mixture
Hazards from the substance or mixture: No specific fire or explosion hazard.
Hazardous combustion products: Decomposition products may include the following materials: carbon oxides
Advice for firefighters
Special precautions for firefighters: Promptly isolate the scene by removing all persons from the vicinity
of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training.
Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and selfcontained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Suitable extinguishing media: In case of fire, use water spray (fog), foam, dry chemical or CO2.
Unsuitable extinguishing media: None known.
Special hazards arising from the substance or mixture
Hazards from the substance or mixture: No specific fire or explosion hazard.
Hazardous combustion products: Decomposition products may include the following materials: carbon oxides
Advice for firefighters
Special precautions for firefighters: Promptly isolate the scene by removing all persons from the vicinity
of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training.
Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and selfcontained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Accidental release measures
Personal precautions, protective equipment and emergency procedures: No action shall be taken involving any personal risk or without
suitable training. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Provide adequate ventilation. Put on appropriate personal protective
equipment.
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Small spill: Move containers from spill area. Vacuum or sweep up material and
place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor.
Large spill: Move containers from spill area. Prevent entry into sewers, water
courses, basements or confined areas. Vacuum or sweep up
material and place in a designated, labelled waste container.
Dispose of via a licensed waste disposal contractor.
suitable training. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Provide adequate ventilation. Put on appropriate personal protective
equipment.
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air).
Methods and materials for containment and cleaning up
Small spill: Move containers from spill area. Vacuum or sweep up material and
place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor.
Large spill: Move containers from spill area. Prevent entry into sewers, water
courses, basements or confined areas. Vacuum or sweep up
material and place in a designated, labelled waste container.
Dispose of via a licensed waste disposal contractor.
Handling and storage
Manufacture and use of this chemical intermediate takes place under strictly controlled conditions, as described in Art. 17/18 REACH. The substance is rigorously contained during manufacturing and use and appropriate risk management measures including PPE (i.g. during charging or sampling) are applied. Occupational exposure is reduced to a minimum and well controlled by measurements. A management system covering all general aspects of a chemical production is in place, especially cleaning and maintenance of plants and equipment. An authorisation scheme based on instructions covering the whole process ensures that only trained and authorised staff handles the substance.
Control parameters
Exposure limit values : Not available.
Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to European Standard EN
689 for methods for the assessment of exposure by inhalation to
chemical agents and national guidance documents for methods for
the determination of hazardous substances.
Risk management measures
Occupational exposure controls
Technical measures:
The substance shall be rigorously contained by technical means
during its whole lifecycle including manufacture, purification,
cleaning and maintenance of equipment, sampling, analysis,
loading and unloading of equipment or vessels, waste disposal or
purification and storage. Procedural and control technologies shall
be used that minimise emission and any resulting exposure. In
cases of accident and where waste is generated, procedural and/
or control technologies shall be used to minimise emissions and
the resulting exposure during purification or cleaning and
maintenance procedures.
Organisational measures : Only properly trained and authorised personnel shall handle the
substance. In the case of cleaning and maintenance works,
special procedures such as purging and washing shall be applied
before the system is opened and entered.
Personal protection measures
Respiratory protection : If exposure cannot be ruled out, e.g. during product transfer,
sampling or maintenance, a well-fitting respiratory mask
conforming to standards or well-fitting respiratory device
conforming to standards must be worn. Respirator selection must
be based on known or anticipated exposure levels, the hazards of
the product and the safe working limits of the selected respirator.
Recommended: Combination filter, e.g. DIN 3181 ABEK if product
forms vapours .
Hand protection: Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if product contact cannot be excluded. After
contamination with product change the gloves immediately and
dispose of them according to relevant national and local regulations. Recommended: (< 1 hour) Butyl rubber - IIR, Viton®
Eye protection: Safety eyewear complying with an approved standard should be
used to avoid exposure to liquid splashes, mists, gases or dusts.
Recommended: Tightly fitting safety goggles.
Skin protection: Wear protective clothing. Personal protective equipment for the
body should be selected based on the task being performed and
the risks involved and should be approved by a specialist before
handling this product.
Recommended: Wear protective clothing.
Hygiene measures: Wash hands, forearms and face thoroughly after handling
chemical products, before eating, smoking and using the lavatory
and at the end of the working period. Appropriate techniques
should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash
stations and safety showers are close to the workstation location.
Environmental exposure controls
Technical measures: Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, special waste
water treatment, fume scrubbers, filters or engineering
modifications to the process equipment will be necessary to reduce
emissions to acceptable levels.
Control parameters
Exposure limit values : Not available.
Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to European Standard EN
689 for methods for the assessment of exposure by inhalation to
chemical agents and national guidance documents for methods for
the determination of hazardous substances.
Risk management measures
Occupational exposure controls
Technical measures:
The substance shall be rigorously contained by technical means
during its whole lifecycle including manufacture, purification,
cleaning and maintenance of equipment, sampling, analysis,
loading and unloading of equipment or vessels, waste disposal or
purification and storage. Procedural and control technologies shall
be used that minimise emission and any resulting exposure. In
cases of accident and where waste is generated, procedural and/
or control technologies shall be used to minimise emissions and
the resulting exposure during purification or cleaning and
maintenance procedures.
Organisational measures : Only properly trained and authorised personnel shall handle the
substance. In the case of cleaning and maintenance works,
special procedures such as purging and washing shall be applied
before the system is opened and entered.
Personal protection measures
Respiratory protection : If exposure cannot be ruled out, e.g. during product transfer,
sampling or maintenance, a well-fitting respiratory mask
conforming to standards or well-fitting respiratory device
conforming to standards must be worn. Respirator selection must
be based on known or anticipated exposure levels, the hazards of
the product and the safe working limits of the selected respirator.
Recommended: Combination filter, e.g. DIN 3181 ABEK if product
forms vapours .
Hand protection: Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if product contact cannot be excluded. After
contamination with product change the gloves immediately and
dispose of them according to relevant national and local regulations. Recommended: (< 1 hour) Butyl rubber - IIR, Viton®
Eye protection: Safety eyewear complying with an approved standard should be
used to avoid exposure to liquid splashes, mists, gases or dusts.
Recommended: Tightly fitting safety goggles.
Skin protection: Wear protective clothing. Personal protective equipment for the
body should be selected based on the task being performed and
the risks involved and should be approved by a specialist before
handling this product.
Recommended: Wear protective clothing.
Hygiene measures: Wash hands, forearms and face thoroughly after handling
chemical products, before eating, smoking and using the lavatory
and at the end of the working period. Appropriate techniques
should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash
stations and safety showers are close to the workstation location.
Environmental exposure controls
Technical measures: Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, special waste
water treatment, fume scrubbers, filters or engineering
modifications to the process equipment will be necessary to reduce
emissions to acceptable levels.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Exposure limit values: Not available
Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to European Standard EN
689 for methods for the assessment of exposure by inhalation to
chemical agents and national guidance documents for methods for
the determination of hazardous substances.
Exposure controls
Risk management measures
Occupational exposure controls
Technical measures: The substance shall be rigorously contained by technical means
during its whole lifecycle including manufacture, purification,
cleaning and maintenance of equipment, sampling, analysis,
loading and unloading of equipment or vessels, waste disposal or
purification and storage. Procedural and control technologies shall
be used that minimise emission and any resulting exposure. In
cases of accident and where waste is generated, procedural and/
or control technologies shall be used to minimise emissions and
the resulting exposure during purification or cleaning and and maintenance procedures.
Organisational measures: Only properly trained and authorised personnel shall handle the
substance. In the case of cleaning and maintenance works,
special procedures such as purging and washing shall be applied
before the system is opened and entered.
Personal protection measures
Respiratory protection:
If exposure cannot be ruled out, e.g. during product transfer,
sampling or maintenance, a well-fitting respiratory mask
conforming to standards or well-fitting respiratory device
conforming to standards must be worn. Respirator selection must
be based on known or anticipated exposure levels, the hazards of
the product and the safe working limits of the selected respirator.
Recommended: Combination filter, e.g. DIN 3181 ABEK if product forms vapours.
Hand protection: Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. After
contamination with product change the gloves immediately and
dispose of them according to relevant national and local regulations
Recommended: (< 1 hour) Butyl rubber - IIR, Viton®
Eye protection: Safety eyewear complying with an approved standard should be
used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts.
Recommended: Tightly fitting safety goggles.
Skin protection: Wear protective clothing. Personal protective equipment for the
body should be selected based on the task being performed and
the risks involved and should be approved by a specialist before
handling this product.
Recommended: Wear protective clothing.
Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techniques should be used to
remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Environmental exposure controls
Technical measures: Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Exposure limit values: Not available
Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to European Standard EN
689 for methods for the assessment of exposure by inhalation to
chemical agents and national guidance documents for methods for
the determination of hazardous substances.
Exposure controls
Risk management measures
Occupational exposure controls
Technical measures: The substance shall be rigorously contained by technical means
during its whole lifecycle including manufacture, purification,
cleaning and maintenance of equipment, sampling, analysis,
loading and unloading of equipment or vessels, waste disposal or
purification and storage. Procedural and control technologies shall
be used that minimise emission and any resulting exposure. In
cases of accident and where waste is generated, procedural and/
or control technologies shall be used to minimise emissions and
the resulting exposure during purification or cleaning and and maintenance procedures.
Organisational measures: Only properly trained and authorised personnel shall handle the
substance. In the case of cleaning and maintenance works,
special procedures such as purging and washing shall be applied
before the system is opened and entered.
Personal protection measures
Respiratory protection:
If exposure cannot be ruled out, e.g. during product transfer,
sampling or maintenance, a well-fitting respiratory mask
conforming to standards or well-fitting respiratory device
conforming to standards must be worn. Respirator selection must
be based on known or anticipated exposure levels, the hazards of
the product and the safe working limits of the selected respirator.
Recommended: Combination filter, e.g. DIN 3181 ABEK if product forms vapours.
Hand protection: Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. After
contamination with product change the gloves immediately and
dispose of them according to relevant national and local regulations
Recommended: (< 1 hour) Butyl rubber - IIR, Viton®
Eye protection: Safety eyewear complying with an approved standard should be
used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts.
Recommended: Tightly fitting safety goggles.
Skin protection: Wear protective clothing. Personal protective equipment for the
body should be selected based on the task being performed and
the risks involved and should be approved by a specialist before
handling this product.
Recommended: Wear protective clothing.
Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techniques should be used to
remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Environmental exposure controls
Technical measures: Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Stability and reactivity
Reactivity: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability: The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid: In the case of dusty organic products the possibility of a dust
explosion should always be considered. No hazardous reactions when used as directed.
Incompatible materials: No specific data.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous
decomposition products should not be produced.
Chemical stability: The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid: In the case of dusty organic products the possibility of a dust
explosion should always be considered. No hazardous reactions when used as directed.
Incompatible materials: No specific data.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous
decomposition products should not be produced.
Disposal considerations
Waste treatment methods
Product
Methods of disposal: Examine possibilities for re-utilisation. Product residues and
uncleaned empty containers should be packaged, sealed, labelled,
and disposed of or recycled according to relevant national and local
regulations. Where large quantities are concerned, consult the
supplier. When uncleaned empty containers are passed on, the
recipient must be warned of any possible hazard that may be caused
by residues. For disposal within the EC, the appropriate code
according to the European Waste List (EWL) should be used. It is
among the tasks of the polluter to assign the waste to waste codes
specific to industrial sectors and processes according to the European Waste List (EWL).
Hazardous waste: The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal: The generation of waste should be avoided or minimised wherever
possible. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible.
Special precautions: This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have
not been cleaned or rinsed out. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.
Product
Methods of disposal: Examine possibilities for re-utilisation. Product residues and
uncleaned empty containers should be packaged, sealed, labelled,
and disposed of or recycled according to relevant national and local
regulations. Where large quantities are concerned, consult the
supplier. When uncleaned empty containers are passed on, the
recipient must be warned of any possible hazard that may be caused
by residues. For disposal within the EC, the appropriate code
according to the European Waste List (EWL) should be used. It is
among the tasks of the polluter to assign the waste to waste codes
specific to industrial sectors and processes according to the European Waste List (EWL).
Hazardous waste: The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal: The generation of waste should be avoided or minimised wherever
possible. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible.
Special precautions: This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have
not been cleaned or rinsed out. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
