Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

If inhaled: If breathed in, move person into fresh air. Artificial respiration and/or oxygen may be necessary. Call a physician immediately.

In case of skin contact:  Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water. Call a physician immediately. Wash contaminated clothing before reuse.

In case of eye contact:  Rinse immediately with plenty of water, also under the eyelids, for at least 5 minutes. Remove contact lenses. If eye irritation persists, consult a specialist.

If swallowed:  If swallowed, rinse mouth with water (only if the person is conscious). Call a physician immediately

Most important symptoms and effects, both acute and delayed

Symptoms: Dilatation of the pupil, Tremors, Sensitisation

Indication of any immediate medical attention and special treatment needed

Treatment: Treat symptomatically.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media:  Water mist Dry powder Foam Carbon dioxide (CO2) Sand Aqueous film forming foam (AFFF). Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media:  Water spray jet

Special hazards arising from the substance or mixture

Specific hazards during firefighting:  Risk of dust explosion.

Hazardous combustion products:  Carbon oxides, Nitrogen oxides (NOx)

Advice for firefighters

Special protective equipment for firefighters:  In the event of fire, wear self-contained breathing apparatus.  

Further information:  Avoid dust formation. In the event of fire, cool tanks with water spray.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Personal precautions:  Avoid dust formation. Avoid breathing dust. Evacuate personnel to safe areas. Keep away from open flames, hot surfaces and sources of ignition.

Environmental precautions:  Should not be released into the environment. Do not flush into surface water or sanitary sewer system.

Methods and material for containment and cleaning up

Methods for cleaning up:  

Large spills: Sweep up or vacuum with HEPA filter or via wet cleaning into suitable containers for disposal. Pick up and arrange without creating dust. Keep in properly labelled containers.

Small spills: Moisten a towel, cover the spill, pick up the spill or use HEPA vacuum.

Large spills and  Small spills: Keep in suitable, closed containers for disposal. Treat recovered material as described in the section "Disposal considerations".

Handling and storage

Precautions for safe handling

Advice on safe handling : Ensure all equipment is electrically grounded before beginning transfer operations. To avoid thermal decomposition, do not overheat. Use personal protective equipment as required. Keep away from heat and sources of ignition. Avoid formation of dust and aerosols. Avoid inhalation, ingestion and contact with skin and eyes.

Advice on protection against fire and explosion :  Avoid dust formation.

Hygiene measures:  Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. When using do not eat, drink or smoke.  

Dust explosion class:  St3  

Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers :  To maintain product quality, do not store in heat or direct sunlight. Store in original container. Keep containers tightly closed in a cool, well-ventilated place. Store at room temperature.  

Recommended storage temperature:  15 - 25 °C

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN2811
Shipping information
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S.
(1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile)
Chemical name:
1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile)
Labels:
6.1
Special provisions / remarks
Remarks:
Tunnel restriction code : (E)
Remarks:
This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN 2811
Shipping information
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S.
(1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile)
Chemical name:
1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile
Labels:
6.1
Special provisions / remarks
Remarks:
This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.

Marine transport (UN RTDG/IMDG)

UN number:
UN 2811
Shipping information
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S.
(1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile)
Chemical name:
1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile
Labels:
6.1
Marine pollutant
Special provisions / remarks
Remarks:
This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of ADR/RID/ADN/IMDG §3.5.1.4 are met.

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 2811
Shipping information
Proper shipping name and description:
TOXIC SOLID, ORGANIC, N.O.S
(1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile)
Chemical name:
(1'-(phenylmethyl)-[1,4'-bipiperidine]-4'-carbonitrile)
Labels:
6.1
Special provisions / remarks
Remarks:
IATA (Cargo)
Packing instruction (cargo aircraft): 677
Packing instruction (LQ): Y645
Packing instruction (EQ): E1

IATA (Passenger)
Packing instruction (passenger aircraft): 670
Packing instruction (LQ): Y645

This substance can be shipped under 'de minimi's quantities' provisions if the net quantity per inner package <= 1mL for liquids or <= 1g for solids and the net quantity per outer package does not exceed 100mL for liquids or 100g for solids and provided packaging provisions of IATA DGR §2.6.10 are met.
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering measures

Engineering controls should be used as the primary means to control possible exposures. Use process enclosures, local exhaust ventilation or other engineering controls to keep exposure levels below recommended exposure limits. All personal protective equipment should be based on a risk assessment. Consult a Environment Health Safety expert if necessary.

Personal protective equipment

Eye protection:  Tightly fitting safety goggles

Hand protection: Material: Nitrile rubber

                          Remarks: Impervious gloves Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).  

Skin and body protection:  closed work clothing disposable one-piece overall

Respiratory protection :  Engineering controls should always be the primary method of controlling exposures. If respiratory protective equipment is needed for certain activities, the type as well as the corresponding protection factor will depend upon the risk assessment and air concentrations, hazards, physical and warning properties of substances present. Use only respiratory protection that conforms to international/ national standards. Suitable mask with particle filter P3

Protective measures :  The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Stability and reactivity

Reactivity: None reasonably foreseeable.

Chemical stability: Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions Hazardous reactions :  Risk of dust explosion.

Conditions to avoid: Heat, flames and sparks. To avoid thermal decomposition, do not overheat.

Materials to avoid:  Oxidizing and spontaneously flammable products

Hazardous decomposition products: Nitrogen oxides (NOx), Carbon oxides

Disposal considerations

Waste treatment methods

Product:  Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities. In accordance with National, Federal, State and Local regulations.

Contaminated packaging :  Empty containers should be taken to an approved waste handling site for recycling or disposal.