Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
General advice: Move out of dangerous area.
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.

If inhaled: If unconscious, place in recovery position and seek medical advice.
If symptoms persist, call a physician.

In case of skin contact: Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty.
If on skin, rinse well with water.
If on clothes, remove clothes.

In case of eye contact: Small amounts splashed into eyes can cause irreversible tissue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.

If swallowed: Keep respiratory tract clear.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.

Most important symptoms and effects, both acute and delayed
Risks: Harmful if swallowed.
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye damage.

Indication of any immediate medical attention and special treatment needed
Treatment: No special measures required.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture
Specific hazards during firefighting: Do not allow run-off from fire-fighting to enter drains or water courses.

Hazardous combustion products: Carbon dioxide (CO2)
Carbon monoxide
Nitrogen oxides (NOx)
Sulphur oxides
Oxides of phosphorus
Metal oxides

Advice for firefighters
Special protective equipment for firefighters: Wear an approved positive pressure self-contained breathing apparatus in addition to standard fire-fighting gear.

Further information: Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Personal precautions: Use personal protective equipment.
Avoid dust formation.
Avoid breathing dust.

Environmental precautions
Environmental precautions: Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform respective authorities.

Methods and material for containment and cleaning up
Methods for cleaning up: Keep in suitable, closed containers for disposal.

Reference to other sections
For personal protection see section ‘Exposure controls/personal protection’.
For disposal considerations see section ‘Disposal considerations’.

Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in
Annex should be consulted for any available use-specific information provided in the Exposure Scenario(s).

Precautions for safe handling
Advice on safe handling: Avoid formation of respirable particles.
Do not breathe vapours/dust.
Avoid contact with skin and eyes.
For personal protection see section ‘Exposure controls/personal protection’.
Smoking, eating and drinking should be prohibited in the application area.
Dispose of rinse water in accordance with local and national regulations.

Advice on protection against fire and explosion: Avoid dust formation. Provide appropriate exhaust ventilation at places where dust is formed.

Hygiene measures: When using do not eat or drink. When using do not smoke.
Wash hands before breaks and at the end of workday.

Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers: Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations / working materials must
comply with the technological safety standards.

Further information on storage stability: No decomposition if stored and applied as directed.

Specific end use(s)
Specific use(s): No data available.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN3077
Shippingopen allclose all
Special provisions / remarks
Remarks:
8, 146, 335, A112, B54, B120, IB8, IP3, N20, N91, T1, TP33
The U.S. Department of Transportation regulations in 49CFR 172.102 permit this
material to ship as an Environmentally Hazardous Substance, Class 9, using Special Provision 146.
Shippingopen allclose all
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
UN3077
Shipping information
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, N.O.S. (Zinc Diisopropyldithiophosphate)
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN3077
Shipping information
Proper shipping name and description:
Environmentally Hazardous Substance, Solid, N.O.S. (Zinc Diisopropyldithiophosphate)
Special provisions / remarks
Remarks:
Passenger aircraft
956: 400 Kg

Cargo aircraft
956: 400 Kg
SpecialProvisionsopen allclose all

Exposure controls / personal protection

The information in this section contains generic advice and guidance. The list of Identified Uses in Annex should be consulted for any available use-specific information provided in the Exposure Scenario(s).

Control parameters
Contains no substances with occupational exposure limit values.

Exposure controls
Engineering measures
Use only with adequate ventilation.
If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Personal protective equipment
Eye protection: Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing problems.
Eye wash bottle with pure water

Hand protection
Material: Use chemical-resistant, impervious gloves.
Wearing time: < 60 min
Remarks: Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
The suitability for a specific workplace should be discussed with the producers of the protective gloves.

Skin and body protection: Dust impervious protective suit
Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Respiratory protection: Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.

Stability and reactivity

Reactivity
No dangerous reaction known under conditions of normal use.

Chemical stability
Stable under normal conditions.

Possibility of hazardous reactions
Hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Stable under recommended storage conditions.
No hazards to be specially mentioned.
Dust may form explosive mixture in air.

Conditions to avoid
Conditions to avoid: No data available

Incompatible materials
Materials to avoid: Reducing agents
Oxidizing agents
Acids and bases

Hazardous decomposition products
No hazardous decomposition products are known.

Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in
Annex should be consulted for any available use-specific information provided in the Exposure Scenario(s).

Waste treatment methods
Product: The product should not be allowed to enter drains, water courses or the soil.
Do not contaminate ponds, waterways or ditches with chemical or used container.
Send to a licensed waste management company.

Contaminated packaging: Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.