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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
comparable to guideline study
Qualifier:
equivalent or similar to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
GLP compliance:
no
Type of method:
gas saturation method
Key result
Temp.:
20 °C
Vapour pressure:
0.21 hPa
Remarks on result:
other: calculated from the regression equation
Key result
Temp.:
25 °C
Vapour pressure:
0.31 hPa
Remarks on result:
other: calculated from the regression equation
Key result
Temp.:
50 °C
Vapour pressure:
1.92 hPa
Remarks on result:
other: calculated from the regression equation

Results:

Temperature

t/°C

Pressure (measured)

p/hPa

Pressure (calculated)

p/hPa

Aberration

%

 29,7

0,40 

0,454

 -11,98

 29,7

 0,55

 0,454

 21,02

 39,1

 0,87

 0,906

 -3,99

 39,1

 0,83

0,906 

 -8,41

 48,8

 1,78

 1,771

 0,52

 48,8

 1,88

 1,771

 6,17

1:

ln(p/Pa) = -1363,17553 + 57397,7861 / T + 206,09998*lnT [T] in Kelvin

mean deviation; : 7,03 %

Scope 29,7 bis 48,8 °C

2:

ln(p/hPa) = 22,1364 - 6942,85 / (273,15 + t) [t] in °C

mean deviation: 8,68 %

Scope 29,7 bis 48,8 °C

Measurement error: Approx.10% of measured value
Conclusions:
The density of the test substance is 0.21, 0.31, and 1.92 hPa at 20, 25, and 50°C, respectively.
Executive summary:

The density of the test substance was measured by gas saturation using a method equivalent to OECD Guideline 104. The density of the test substance is 0.21, 0.31, and 1.92 hPa at 20, 25, and 50°C, respectively.

Description of key information

equivalent to OECD Guideline 104

Key value for chemical safety assessment

Vapour pressure:
0.21 hPa
at the temperature of:
20 °C

Additional information

0.32 hPa at 25°C

1.92 hPa at 50°C