Registration Dossier
Registration Dossier
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EC number: 212-611-1 | CAS number: 831-82-3
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
If on skin
Immediately remove splashed or contaminated clothing including shoes. Shower and rinse contaminated parts of the body with
abundant water (and with soap if available).
Seek for medical attention of irritation appears.
If contact with eyes
Immediately maintain the eye open and rinse abundantly with water.
Ensure complete eye irrigation by maintaining eyelids open and lifted from the eye surface and by moving eyelids occasionally up and down.
Seek for medical attention if pain remains or reappears.
Contact lenses should be removed by a trained person.
If inhaled
If smoke or combustion products are inhaled, move the person to fresh air.
Lie the victim down. Keep the person warm and let the person rest.
Prosthesis like false teeth, that might block respiratory tract, soud e removed if possible before starting first aid procedure.
If availlable, provide oxygen by a trained person. If repiration is weak or has topped, ensure that the repiratory tract is clear and start reanimation (preferably with autonomous system or masks). Start CPR if necessary.
Immediately transfer the person to the hospital or to a doctor.
If swallowed
For advice, contact Anti-poison center or call a doctor.
An emergency treatment at the hospital is likely needed.
If consicous, give water. Induce vomitting with fingers down the throat, only if the person is conscious.
Lean the patient forwad or place him/her on its right side (head in down position if possible) to maintain the respiratory tract open and avoid aspiration.
Relark: wear protective glove when unducing vomitting by mechanical mean.
Seek for immediate medical attention. Meanwhile, trained staff in first aid should treat the patient depending on its condition.
If medical attention is quickly available, a copy of the SDS should be given to the doctor. Other actions will be the responsiility of the medical staff.
If medical attention is not available in the workplace or around, immediately transfer the person to the hospital with a copy of the SDS
Indication of any immediate medical attention and special treatment needed
for poisons (in case of no treatment)
Basic treatment
Establish clear respiratory tract, with suction if necessary
Monitor any signs of respiratory failures and assist with ventilation if necessary
Provide oxygen with a mask with non return valve at 10 to 15 L/min
Monitor and treat against shock if necessary
Monitor and treat against pulmonary edema if necessary
Anticipate any crisis
DO NOT use emetic treatment. If ingestion is suspected, rince the mouth and give up to 200 mL of water (5 mL/Kg recommended) to dilute the product when the patient is able to swallow, have a strong pharyngeal reflex and do not dribble.
Advanced treatment
Consider orotracheal or nasotracheal intubation to control the respiratory tract when the patient is unconscious or after a respiratory failure occured.
Continuous positive airway pressure using a mask with valv could be useful.
Monitor and treat against arythmia if necessary
Start IV D5W TKO. If hypovolemia signes are visible, use a Ringers milky solution.A fluid overload might lead to complications.
Drug therpay should be considered for pulmonary edema.
Hypotension without signs of hypovolemia could require vasopressors. Hypotension with hypovolemia signs requires fluid administration with precaution.A fluid overload might lead to complications.
Treat crises with diazepam.
Proparacaine chlorhydrate should be used to help irrigating the eyes
BRONSTEIN, A.C. and CURRANCE, P.L. EMERGENCY CARE FOR HAZARDOUS MATERIALS EXPOSURE: 2nd Ed.1994
Fire-fighting measures
Extinguishing media
Appropriate means of extnguishing fires
physical foam, dry chemical powder, BCF (if allowed), carbon dioxide.
Special hazards arising from the subtance or mixture
Fire incompatibility
Avoid contact with oxdising agents i.e. nitrates, oxidising acids, bleach containing chloride, swimming poll chloride etc. Ignition can occur.
Advice for firefighters
Fire fighting
Call firefighters and indicate the place and nature of the risk
Wear respiratory devices and appropriate protective gloves.
Avoid by any means spilling and contamination of water drains and evacuation system.
Use fine spray water to control the fire and cool down adjacent areas.
Fire/explosion risk
Solid fuel that burns but hardly propagate flames
Avoid dust generation, particularly dust cloud in non-ventilated or confined area. Dust clouds can form an explosive mix with air or with any other ignition sources, i.e. flames or sparks, that could intiate a fire or an explostion. Fine dust coulds can burn quickly and strongly if initiated.
Dry dust can also gain electrostatic charge by turbulences, land transport, discharge in exhaust ducting and during transport.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Minor spilling
Remove ignition sources
Immediatly clean the splashes
Avoid contact with skin and eyes
Control cntact with individuals with using potective equipment
Major spilling
Moderate risk
WARNING: Inform the personal in the area
Alert emergecy services and indicate the place and the nature of the risk
Advice for individual protection equipement is given in section 8.
Handling and storage
Precautions for safe handling
Safe handling
Avoid any contact, including inhalation
Wear protection colthes in case of risk of exposure
Use in well venitlated area
Prenvent concentration in holes or hollows
Other data
Store in the original packaging, closed appropriately.
Maintain containers well sealed
Store in a dry, cool and ventilated room.
Store away from incompatible materials and away from recipients containing food.
Conditions for safe storage, including any incompatibilities
Adapted Packaging materials
Polyethylen or polypropylen containers
Check that every container is clearly labelled and without any leak.
Storage incompatibilities
Avoid reaction with oxidising agents
Avoid strong base
Transport information
Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Remarksopen allclose all
Shippingopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure controls
Appropriate engineering controls
Local exhaust ventilation is required wen solids like powder or cristals are manipulated, even if particles are particulary important in size considering a fraction of it with transform into powder by manual friction.
Exhaust ventilation should be planned to avoid accumulatio and particle recylcing at the work place.
If, even with the exhaust ventialtion, the product concentrate in the air, repisratory protection should be coniedre.
Individual protection
Apropriate gloves, repiratory mask, safety goggles, protection clothing and shoes
Eye/Face protection
Safety goggles with side portection
Chemical mask
Contact lenses are a particlar risk: soft lenses can absorb irritant products and all lenses concentrate product. DO NOT wear contact lenses.
Skin protection: see hand protection
Hand protection
Note: the product can cause skin sensitisation in predisposed people. Attention should be taken when a person take out its gloves and portection equipment to avoid any possible contact with skin.
Type of gloves and time to keep them is dependant on the use.
Body portection: see other protection
Other protection:
full uniform
PVC apron
Protective cream
Cleaning cream for skin
Stability and reactivity
Reactivity
See Handling and storage section
Chemical stability
Existence of incompatible materials
The product is consider stable.
Hazardous polymerisation won't occur.
Possibility of hazardous reactions
See Handling and storage section
Conditions to avoid
See Handling and storage section
Incompatible materials
See Handling and storage section
Hazardous decomposition products
See fire-fighting measure
Disposal considerations
Waste treatment methods
Product and container elimination
Drill the containers to avoid re-use
Regulation regarding waste elimination can be different depending on the countries, regions or domains. Each user should follow the local regulation.
In some particular cases, some waste can be monitored more closely.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
