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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flammability

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Administrative data

Endpoint:
pyrophoric liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
15 August 2017 to April 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2018
Report date:
2018

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.13 (Pyrophoric Properties of Solids and Liquids)
Version / remarks:
Council Regulation 440/2008, 30 May 2008
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Other quality assurance:
ISO/IEC 17025 (General requirements for the competence of testing and calibration laboratories)

Test material

Constituent 1
Chemical structure
Reference substance name:
1,2,3-tris(2-octyldodecyl) 2-hydroxypropane-1,2,3-tricarboxylate
EC Number:
603-121-2
Cas Number:
126121-35-5
Molecular formula:
C66H128O7
IUPAC Name:
1,2,3-tris(2-octyldodecyl) 2-hydroxypropane-1,2,3-tricarboxylate
Test material form:
liquid
Details on test material:
Tris(octyldodecyl) citrate 99.87 %
Bis(octyldodecyl) citrate 0.13 %
Specific details on test material used for the study:
The test substance, 2,3-Propanetricarboxylic acid, 2-hydroxy-1,2,3-tris(2-octyldodecyl) ester was allocated the code ESTS 69/17 for reference throughout the study.
Name: 2,3-Propanetricarboxylic acid, 2-hydroxy-1,2,3-tris(2-octyldodecyl) ester (Citmol 320)
Physical state: Clear, faintly yellow liquid
Purity: 99.39%
Molecular weight: 1033.74 g/mol
Storage conditions: Room temperature (15 to 30°C)

Results and discussion

Pyrophoric liquidsopen allclose all
Key result
Test procedure:
ignition time on contact with air
Remarks on result:
no ignition within 5 minutes
Key result
Test procedure:
effect on filter paper
Remarks on result:
no charring

Any other information on results incl. tables

No ignitions were observed for the first tests with kieselguhr in crucibles and no ignition or charring was observed during the second tests with filter paper. The test substance is not considered to have pyrophoric properties. The measured room temperature during testing was 20°C.

Applicant's summary and conclusion

Interpretation of results:
GHS criteria not met
Conclusions:
The test substance was found not to have an ignition time in contact with air, under the conditions of the test.
Executive summary:

In this guideline (EU A.13) study, [conducted with GLP certification], the test substance was found not to have an ignition time in contact with air.