Registration Dossier
Registration Dossier
Diss Factsheets
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EC number: 242-042-4 | CAS number: 18162-48-6
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data

Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Take off all contaminated clothing immediately.
Inhalation:
In case product dust is released:
Possible discomfort: severe irritation of mucous lining (nose, throat, eyes), cough, sneezing, flow of tears
Move victims into fresh air.
If breathing difficulties occur:
Keep patient half sitting with upper body raised.
Call a physician immediately.
Skin contact:
Wash off immediately with plenty of water.
Consult a physician.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
Continue rinsing process with eye rinsing solution.
Protect unharmed eye.
Call ambulance. (Cue: caustic burn of the eyes)
Immediate further treatment in ophthalmic hospital/ ophthalmologist.
Continue rinsing eye until arrival at ophthalmic hospital.
Ingestion:
Do NOT induce vomiting.
Only when patient fully conscious:
Have the mouth rinsed with water.
Have patient drink plenty of water in small sips.
Notify ambulance immediately (keyword: chemical burn).
Most important symptoms and effects, both acute and delayed:
Symptoms
None known
Hazards
None known
Indication of any immediate medical attention and special treatment needed
Therapy as for chemical burn.
If substance has been swallowed:
Early endoscopy in order to assess mucosa lesions in the oesophagus and stomach which may appear.
If necessary, suck away leftover substance.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
water spray
Carbon dioxide (CO2)
Dry powder
Foam
Unsuitable extinguishing media: High volume water jet
Special hazards arising from the substance or mixture
In the case of fire, the following hazardous smoke fumes may be produced: hydrogen chloride.
carbon monoxide, carbon dioxide
organic products of decomposition
Advice for firefighters
Water used to extinguish fire should not enter drainage systems, soil or stretches of water.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
In the case of fire, wear respiratory protective equipment independent of surrounding air and chemical protective suit.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment.
Ensure adequate ventilation.
Avoid contact with the skin and the eyes.
Environmental precautions
Do not allow entrance in sewage water, soil stretches of water, groundwater, drainage systems.
Methods and material for containment and cleaning up
Pick up mechanically. Pour into containers which can be tightly sealed. Dispose of absorbed material in accordance with the regulations.
Use only non-sparking tools.
Handling and storage
Precautions for safe handling
Provide good ventilation or extraction.
In case of insufficient ventilation, wear suitable respiratory equipment.
Handle under inert gas
Do not use sparking tools.
Conditions for safe storage, including any incompatibilities
Advice on protection against fire and explosion
Take precautionary measures against static discharges.
Keep away from sources of ignition - No smoking.
When repairs of the production system are to be made (e.g. welding work), the section to be repaired must be essentially free of product.
Storage
Keep containers tightly closed in a cool, well-ventilated place.
Keep away from direct sunlight.
Protect from moisture.
Keep at temperatures of between 2 °C and 8 °C.
Under inert gas keep in a cool place.
Do not store together with: oxidizing agents
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Engineering measures:
Ensure good ventilation during processing.
Personal protective equipment
Respiratory protection:
In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded:
use respiratory equipment with suitable filter (filter type ABEK) or wear a self contained respiratory apparatus
Use only respiratory protection equipment with CE-symbol including four digit test number.
The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, self-contained breathing apparatus must be used.
Note time limit for wearing respiratory protective equipment.
Hand protection:
Selection of protective gloves to meet the requirements of specific workplaces.
Suitability for specific workplaces should be clarified with protective glove manufacturers.
Please observe that the daily duration of usage of a chemical protective glove is in practice far shorter due to the many influencing factors (e.g. temperature, mechanical strain on the glove material) than the permeation time determined acc. EN 374.
The material thickness and rupture time data do not apply to non-solute solids / dusts.
Eye protection:
close-fitting protective goggles (e.g. closed goggles) or face protection
Skin and body protection
When handling larger quantities:
One-way protective suit (dust-sealed)
Flame retardant antistatic protective clothing.
Hygiene measures:
When using, do not eat, drink or smoke. Wash face and/or hands before break and end of work.
Remove immediately all contaminated clothing.
Dispose of promptly.
Protective measures:
Handle in accordance with good industrial hygiene and safety practice.
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
If workplace exposure limits are exceeded and/or larger amounts are released (leakage, spilling, dust) the indicated respiratory protection should be used.
If there is the possibility of skin/eye contact, the indicated hand/eye/body protection should be used.
Use protective clothing / face shield if necessary.
Do not breathe vapours/dust.
Avoid contact with skin and eyes.
Stability and reactivity
Reactivity:
No dangerous reaction known under conditions of normal use.
Chemical stability:
Stable under recommended storage conditions.
Possibility of hazardous reactions
Possibility of hazardous reactions
No dangerous reactions have been known to occur in conjunction with the proper use to the product.
Conditions to avoid:
Keep away from heat and sources of ignition.
Keep away from direct sunlight.
Protect from moisture.
Incompatible materials:
Water, Bases, Metals, Alcohols, oxidizing agents
Hazardous decomposition products:
hydrogen chloride
Disposal considerations
Waste treatment methods
Product:
Confer with the producer.
Special treatment is necessary.
Uncleaned packaging:
Do not re-use empty containers.
Confer with the producer.
If there is product residue in the emptied container, follow directions for handling on the container's label.
Incorrect disposal or reuse of this container is illegal and can be dangerous.
Other countries: observe the national regulations.
Waste Key Number:
No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer.
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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