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Reference
Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
11 October 2018 to 12 October 2018
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.16 (Relative Self-Ignition Temperature for Solids)
Version / remarks:
2008
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Key result
Relative self-ignition temperature:
> 70 °C
Remarks on result:
no self-ignition observed up to the melting point

Three replicate tests were performed. No relative self-ignition temperature of the test material was observed up to the melting of test material (around 70 °C) and is therefore considered not auto-flammable.

Conclusions:
Under the conditions of the study no relative self-ignition temperature of the test material was observed up to the melting of test material (around 70 °C) and is therefore considered not auto-flammable.
Executive summary:

The relative self-ignition temperature of the test material was assessed in accordance with standardised guideline EU Method A.16 and in compliance with GLP.

A specific amount of the test material was placed in a wire-mesh cube into an oven at room temperature; the temperature difference/time curve of the sample of test material was recorded while the temperature of the oven was increased from about 30°C to 400°C (or to above the melting point), at a rate of 0.5 °C/minute. For the purpose of this test, the temperature of the oven at which the sample temperature reaches 400°C by self-heating is called the self-ignition temperature.

Under the conditions of the study no relative self-ignition temperature of the test material was observed up to the melting of test material (around 70°C) and is therefore considered not auto-flammable.

Description of key information

Under the conditions of the study no relative self-ignition temperature of the test material was observed up to the melting of test material (around 70°C) and is therefore considered not auto-flammable.

Key value for chemical safety assessment

Additional information

The relative self-ignition temperature of the test material was assessed in accordance with standardised guideline EU Method A.16 and in compliance with GLP. The study was awarded a reliability score of 1 in accordance with the criteria set forth by Klimisch et al. (1997).

A specific amount of the test material was placed in a wire-mesh cube into an oven at room temperature; the temperature difference/time curve of the sample of test material was recorded while the temperature of the oven was increased from about 30°C to 400°C (or to above the melting point), at a rate of 0.5°C/minute. For the purpose of this test, the temperature of the oven at which the sample temperature reaches 400°C by self-heating is called the self-ignition temperature.

Under the conditions of the study no relative self-ignition temperature of the test material was observed up to the melting of test material (around 70°C) and is therefore considered not auto-flammable.