Naphtha fraction, waste plastic derived, hydrothermal conversion

Guidance on Safe Use

First-aid measures

General notes

Self-protection of the first aider.

Take off immediately all contaminated clothing.

Remove affected person from the danger area and lay down.

Do not leave affected person unattended.

In all cases of doubt, or when symptoms persist, seek medical advice.

Following inhalation

Provide fresh air.

If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions.

Mouth to mouth resuscitation should be avoided. Use alternative methods, preferably with oxygen or

compressed air driven apparatus.

Following skin contact

Wash with plenty of soap and water.

If skin irritation occurs: Get medical advice/attention.

Following eye contact

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Remove contact lenses, if present and easy to do. Continue rinsing.

Following ingestion

Rinse mouth. Do not induce vomiting.

Call a physician immediately.

Notes for the doctor

None.

Most important symptoms and effects, both acute and delayed

Death following aspiration.

Irritant to skin.

Narcotic effects.

Vertigo.

Drowsiness.

Dizziness.

Indication of any immediate medical attention and special treatment needed

Symptoms may develop several hours following exposure; medical observation therefore necessary

for at least 48 hours.

Subsequent observance for pneumonia and pulmonary oedema.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media

water spray, alcohol resistant foam, fire extinguishing powder, carbon dioxide (CO2)

Unsuitable extinguishing media

water jet

Special hazards arising from the substance or mixture

In case of insufficient ventilation and/or in use, may form flammable/explosive vapour-air mixture.

Solvent vapours are heavier than air and may spread along floors.

Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits

and shafts, are particularly prone to the presence of flammable substances or mixtures.

Hazardous combustion products

carbon monoxide (CO), carbon dioxide (CO2), pyrolysis products, toxic

Advice for firefighters

Keep containers cool with water spray.

In case of fire and/or explosion do not breathe fumes.

Co-ordinate firefighting measures to the fire surroundings.

Do not allow firefighting water to enter drains or water courses.

Collect contaminated firefighting water separately.

Fight fire with normal precautions from a reasonable distance.

Containments may explode when heated.

Special protective equipment for firefighters

use suitable breathing apparatus and suitable protective clothing if risk of contact with substance.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

Remove persons to safety.

Ventilate affected area.

Avoid contact with skin and eyes.

Avoid breathing mist/vapours/spray.

Wearing of suitable protective equipment (including personal protective equipment referred to under

Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing.

For emergency responders

Wear breathing apparatus if exposed to vapours/dust/spray/gases.

Chemical protection suit.

Environmental precautions

Keep away from drains, surface and ground water.

Retain contaminated washing water and dispose of it.

If substance has entered a water course or sewer, inform the responsible authority.

Methods and material for containment and cleaning up

Advice on how to clean up a spill

Collect spillage.

Absorbent material (e.g. sand, diatomaceous earth, acid binder, universal binder, sawdust, etc.).

Appropriate containment techniques

Use of adsorbent materials.

Bunding.

Remove from the water surface (e.g. skimming, sucking).

Other information relating to spills and releases

Place in appropriate containers for disposal.

Ventilate affected area.

Keep away from sources of ignition - No smoking.

Handling and storage

Precautions for safe handling

Provision of sufficient ventilation.

Avoid contact with skin and eyes.

Avoid breathing mist/vapours/spray.

Handle and open container with care.

Measures to prevent fire as well as aerosol and dust generation

Use local and general ventilation.

Keep away from sources of ignition - No smoking.

Take precautionary measures against static discharge.

Due to danger of explosion, prevent leakage of vapours into cellars, flues and ditches.

Ground/bond container and receiving equipment.

Use explosion-proof electrical/ventilating/lighting/equipment.

Use only non-sparking tools.

Specific notes/details

Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits

and shafts, are particularly prone to the presence of flammable substances or mixtures.

Vapours are heavier than air, spread along floors and form explosive mixtures with air.

Measures to protect the environment

Avoid release to the environment.

Advice on general occupational hygiene

Do not eat, drink and smoke in work areas.

Wash hands after use.

Preventive skin protection (barrier creams/ointments) is recommended.

Remove contaminated clothing and protective equipment before entering eating areas.

Conditions for safe storage, including any incompatibilities

Explosive atmospheres

Keep container tightly closed and in a well-ventilated place.

Use local and general ventilation.

Keep cool.

Protect from sunlight.

Flammability hazards

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Take precautionary measures against static discharge.

Ground/bond container and receiving equipment.

Protect from sunlight.

Protect against external exposure, such as

heat

Consideration of other advice

Keep away from food, drink and animal feedingstuffs.

Ventilation requirements

Provision of sufficient ventilation.

Specific designs for storage rooms or vessels

Keep in a cool, well-ventilated place.

Packaging compatibilities

Only packagings which are approved (e.g. acc. to ADR) may be used.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

1268

Shipping information

Proper shipping name and description:

UN1268, PETROLEUM DISTILLATES, N.O.S., 3, II, (D/E), environmentally hazardous, special provision 640C

Particulars in the transport document Special provision 640C

Labels:

3, fish and tree

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

1268

Shipping information

Proper shipping name and description:

UN1268, PETROLEUM DISTILLATES, N.O.S., 3, II, (D/E), environmentally hazardous, special provision 640C

Particulars in the transport document Special provision 640C

Labels:

3, fish and tree

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

1268

Shipping information

Proper shipping name and description:

UN1268, PETROLEUM DISTILLATES, N.O.S., 3, II, <15°C c.c., MARINE POLLUTANT

Labels:

3, fish and tree

Marine pollutant

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

1268

Shipping information

Proper shipping name and description:

UN1268, Petroleum distillates, n.o.s., 3, II

Labels:

3

Remarks

SpecialProvisions

Exposure controls / personal protection

Exposure controls

Appropriate engineering controls

General ventilation.

Individual protection measures (personal protective equipment)

Wear suitable protective clothing.

Eye/face protection

Wear eye/face protection.

Hand protection

Protective gloves

Material thickness Breakthrough times of the glove material

Nitrile ≥ 0,45 mm >480 minutes (permeation: level 6)

FKM: fluoro-elastomer ≥ 0,65 mm >480 minutes (permeation: level 6)

NBR: acrylonitrile-butadiene rubber ≥ 0,65 mm >240 minutes (permeation: level 5)

Wear suitable gloves.

Check leak-tightness/impermeability prior to use.

In the case of wanting to use the gloves again, clean them before taking off and air them well.

For special purposes, it is recommended to check the resistance to chemicals of the protective gloves

mentioned above together with the supplier of these gloves.

Respiratory protection

In case of inadequate ventilation wear respiratory protection.

Type: A-P2 (combined filters against particles and organic gases and vapours, colour code: Brown/

White).

Environmental exposure controls

Use appropriate container to avoid environmental contamination.

Keep away from drains, surface and ground water.

Stability and reactivity

Reactivity

If heated:

risk of ignition

Chemical stability

See below "Conditions to avoid".

Possibility of hazardous reactions

No known hazardous reactions

Conditions to avoid

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Take precautionary measures against static discharge.

Use explosion-proof electrical/ventilating/lighting/equipment.

Use only non-sparking tools.

Incompatible materials

oxidisers

Hazardous decomposition products

Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill

and heating are not known.

Disposal considerations

Waste treatment methods

This material and its container must be disposed of as hazardous waste.

Sewage disposal-relevant information

Do not empty into drains.

Waste treatment of containers/packagings

Completely emptied packages can be recycled.

Handle contaminated packages in the same way as the substance itself.

Remarks

Please consider the relevant national or regional provisions.