Registration Dossier
Registration Dossier
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EC number: 226-166-6 | CAS number: 5308-25-8
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel should pay attention to their own safety.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. Pulmonary odema prophylaxis. Medical monitoring for at least 24 hours.
Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel should pay attention to their own safety.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. Pulmonary odema prophylaxis. Medical monitoring for at least 24 hours.
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media:
water spray, foam, dry powder
5.2. Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.
5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Suitable extinguishing media:
water spray, foam, dry powder
5.2. Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.
5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
6.2. Environmental precautions
Do not discharge into drains/surface waters/groundwater.
6.3. Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).
Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.
6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.
Avoid inhalation. Avoid contact with the skin, eyes and clothing.
6.2. Environmental precautions
Do not discharge into drains/surface waters/groundwater.
6.3. Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).
Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.
6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.
Handling and storage
7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.
Protection against fire and explosion:
The product is combustible. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Temperature class: T2 (Autoignition temperature >300 °C).
7.2. Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Suitable materials for containers: Stainless steel 1.4301 (V2), Stainless steel 1.4401, glass, tinned carbon steel (Tinplate), Carbon steel (Iron)
Unsuitable materials for containers: Low density polyethylene (LDPE), High density polyethylene (HDPE)
Further information on storage conditions: Avoid all sources of ignition: heat, sparks, open flame. Keep container tightly closed in a cool, well-ventilated place.
Storage class according to TRGS 510 (originally VCI, Germany): (3) Flammable liquids
Storage stability:
Storage temperature: 20 °C
Storage duration: 36 Months
May discolour after lengthy storage.
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
7.3. Specific end use(s)
See exposure scenario(s) in the attachment to this safety data sheet.
Ensure thorough ventilation of stores and work areas. Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.
Protection against fire and explosion:
The product is combustible. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Temperature class: T2 (Autoignition temperature >300 °C).
7.2. Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Suitable materials for containers: Stainless steel 1.4301 (V2), Stainless steel 1.4401, glass, tinned carbon steel (Tinplate), Carbon steel (Iron)
Unsuitable materials for containers: Low density polyethylene (LDPE), High density polyethylene (HDPE)
Further information on storage conditions: Avoid all sources of ignition: heat, sparks, open flame. Keep container tightly closed in a cool, well-ventilated place.
Storage class according to TRGS 510 (originally VCI, Germany): (3) Flammable liquids
Storage stability:
Storage temperature: 20 °C
Storage duration: 36 Months
May discolour after lengthy storage.
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
7.3. Specific end use(s)
See exposure scenario(s) in the attachment to this safety data sheet.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
chemical-protection suit (f.e. according to EN 14605)
General safety and hygiene measures
Avoid contact with the skin, eyes and clothing. Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Take off immediately all contaminated clothing. Store work clothing separately.
Stability and reactivity
10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
Corrosive effects to metal are not anticipated. In the presence of water or moisture metal corrosion cannot be excluded.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.
10.2. Chemical stability
The product is chemically stable.
10.3. Possibility of hazardous reactions
Strong exothermic reaction with acids.
10.4. Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame.
10.5. Incompatible materials
Substances to avoid:
nitrosating agents, acids
10.6. Hazardous decomposition products
Possible thermal decomposition products:
carbon oxides, nitrogen oxides
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
Corrosive effects to metal are not anticipated. In the presence of water or moisture metal corrosion cannot be excluded.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.
10.2. Chemical stability
The product is chemically stable.
10.3. Possibility of hazardous reactions
Strong exothermic reaction with acids.
10.4. Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame.
10.5. Incompatible materials
Substances to avoid:
nitrosating agents, acids
10.6. Hazardous decomposition products
Possible thermal decomposition products:
carbon oxides, nitrogen oxides
Disposal considerations
Dispose according to local regulations.
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