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Physical & Chemical properties

Water solubility

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Reference
Endpoint:
water solubility
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 105 (Water Solubility)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.6 (Water Solubility)
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
flask method
Specific details on test material used for the study:
SOURCE OF TEST MATERIAL
- Source and lot/batch number of test material: 4133/00-K0
- Expiration date of the lot/batch: June 08, 2021
- Purity test date: Certificate dated from December 03, 2020, Umicore, Germany

STABILITY AND STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: Room temperature (10°C to 30 °C), dark, dry

FORM OF TEST MATERIAL
- Content: Pt 1.820 % (ICP-OES)
- Form: liquid
- Appearance: Pale yellow clear liquid
Water solubility:
> 1 000 g/L
Temp.:
20 °C
pH:
< 1.1

Individual results


Preliminary test


In a stepwise procedure, increasing volumes of demineralized water were added at room temperature to a defined amount of the test item. After each addition of an amount of water the mixture was stirred and visually checked for any undissolved particles.


Table 1: Results of the preliminary test






































Amount of test item


/ mg



Added volume of demineralized water


/ ml



Total volume of demineralized water


/ ml



Appearance of mixture



109.2



0.1



0.1



dissolved



0.4



0.5



dissolved



0.5



1.0



dissolved



1.0



2



dissolved



8.0



10



dissolved



The preliminary test showed that the water solubility of the test item was > 1000 g/l. For this reason, instead of the main test a miscibility test was performed as described in chapter 4.1.2. Within the miscibility test it was investigated if the test item was miscible with demineralized water in different ratios.


Miscibility test


Table 2: Results of the miscibility test










































Experiment



A



B



C



Amount of test item (ml)



0.5



2.5



4.5



Amount of demin. water (ml)



4.5



2.5



0.5



Ratio



1:9



1:1



9:1



pH value



1.1



0.4



0.2



Appearance of the mixture



dissolved



dissolved



dissolved



The test item Platinum concentrate P was miscible with water at room temperature (T = 23.7 °C) in all tested ratios (1:1, 1:9, 9:1).


 

Conclusions:
The water solubility of the test item at 20 °C was determined to be > 1000 g/l.
Executive summary:
Huber-Lohr (2021) is a GLP-compliant study following OECD guideline 105 and EU method A6. It is reliable without restrictions and can be used as a key study for this endpoint. The flask method was performed. The water solubility of the test item at 20 °C was determined to be > 1000 g/l.

Description of key information

The water solubility of the test item at 20 °C was determined to be > 1000 g/l.

Key value for chemical safety assessment

Water solubility:
1 000 g/L
at the temperature of:
20 °C

Additional information

Huber-Lohr (2021) is a GLP-compliant study following OECD guideline 105 and EU method A6. It is reliable without restrictions and can be used as a key study for this endpoint. The flask method was performed. The water solubility of the test item at 20 °C was determined to be > 1000 g/l.