STABILISATOR MASTERBATCH C 133

Guidance on Safe Use

First-aid measures

Emergency measure - Inhalation: In case of irritation of the respiratory tract consult a

doctor.

Emergency measure - Eyes: In case of eye contact  rinse carefully and thoroughly with

water and seek medical advice.

Emergency measure - Skin: In case of skin contact wipe off mechanically and wash

afflicted areas thorougly with soap and plenty of water.

Emergency measure - Ingestion: In case of swallowing consult a doctor.

Fire-fighting measures

Recommended extinguishing agent: There is no restriction in the choice of extinguishing

agents.

Product arising from burning: CO, CO2, HCl, Phosphoroxide and water containing gases arise

from burning or pyrolysis of substances with a chemical

composition like this new substance.

Product determined by test: N

Protective equipment: Respiratory protection and protectiv clothing, depending on

the scale of fire and local conditions.

Accidental release measures

Emergency measures in case of spillage: Substance may not come into the waste water system. Solvent

containing material must be kept away from ignition sources;

avoid inhalation and contact with skin.

Keep unauthorized people away. Remove mechanically; cover

residues with chemical binder or, if necessary with dry sand

and store in closed containers. Further disposal by

incineration.

Handling and storage

Handling: The substance should be handled with good hygiene

precautions. Inhalation of vapours and skin and eye contact

must be avoided. Suitable safety goggles, clothing and

gloves are recommended if there is a possible contact with

the product (the substance is slightly irritant to the

eyes). Provide effective ventilation (at spraying it is

necessary to use respiratory protection). Keep away from

foodstuff.

Processing may only be accomplished in explosion proof rooms

due to toluene and styrene as solvents in the preparations

(flash point 6°C and 32°C). At contact with solvent

containing materials  all necessary measures have to be

taken; sufficient ventilation or exhaustion is required.

Wash hands before breaks and at end of work.

Take off immediately all contaminated clothing. Separate

keeping of working clothings. Explosion protection is

required when handling  toluene and styrene-containing

material.

Storage: The product must be stored dry and at room  temperature in

tightly closed containers. Storage rooms should be treated

with common hygiene precautions.

After taking out material containers have to be closed

properly. Residues outside the containers must be avoided.

Preparations with solvents are flammable;  remove sources of

fire; take measures against electrostatic charging.

Pentration of soil with material or extinguishing water must

be avoided.

Packaging of the substance and or preparation: Metal cans (1 l, 5 l).

Transport information

Shipping

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

Shipping

Remarks

Air transport (UN RTDG/ICAO/IATA)

Shipping

Special provisions / remarks

Remarks:

Transport code: 1993
Transport: Pure substance: Due to the eye irritation and liquid form of
the substance it must be stored in tightly closed containers
even for internal transportation.(classification GGVS/GGVE
class 3, number 31C). Suitable unbreakable packaging,
protection against falling down and proper labelling assure
save transport. All containers must be labelled according to
the regulations.

Opend containers must be closed carefully to avoid spillage.
Keep dry and separate from foodstuffs.

SpecialProvisions

Stability and reactivity

Danger other than fire: unknown

Chemical reaction with water: No dangerous reaction with water.

The substance decomposes in water; clouding and formation of

white precipitate; discoloration (green/blue) and increase

of the pH-value. Saturated solutions in water change the

ratio between copper and phophorous in comparison to the

pure substance; this is a sign of instability.

Dust explosion: not applicable - liquid

Dust explosion determined by test: N

Disposal considerations

Industry - Possibility of recovery/recycling: No possibility of recovery. Polluted material must be

incinerated.

Only small amounts of appr. 3 l are produced and used.

Industry - Possibility of neutralisation: No special methods are known to neutralize the dangers

arising from the substance.

Industry - Possibility of destruction: controlled discharge: No dumping on waste disposal sites.

Industry - Possibility of destruction - incineration: Incineration is the favorite and recommended way of removal.

The thereby produced waste gases contain hydrogen cloride.

Industry - Possibility of destruction - water purification: At this time there is no information about the removal rate

by waste water treatment. In water the substance decomposes

and a precipitate is developped within several hours. The

pH-value is changing.

At appropriate introduction of small concentrations in

adapted waste water treatment plants detoriation of the

power of the activated sludge is not to be expected.

Public at large - Possibility of recovery/recycling: The substance is not used in public area.