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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Additional information on environmental fate and behaviour

Administrative data

Endpoint:
additional information on environmental fate and behaviour
Type of information:
other: BUA report
Adequacy of study:
other information
Reliability:
other: BUA report
Rationale for reliability incl. deficiencies:
other: No reliability is given as this is a summary entry for the BUA report.

Data source

Referenceopen allclose all

Reference Type:
secondary source
Title:
2,4-Dichloranilin; 2,5-Dichloranilin; 3,4-Dichloranilin
Author:
Beratergremium für umweltrelevante Altstoffe (BUA)
Year:
1994
Bibliographic source:
Wissenschaftliche Verlagsgesellschaft, BUA report 140
Reference Type:
publication
Title:
Pesticide transformations: production of chloroazobenzenes from chloroanilines
Author:
Bartha R, Linke HAB, Pramer D
Year:
1968
Bibliographic source:
Science 161, 582-583
Reference Type:
publication
Title:
Biochemical transformations of herbicide-derived anilines: requirements of molecular configuration.
Author:
Bordeleau LM and Bartha R
Year:
1972
Bibliographic source:
Can. J. Microbiol. 18, 1873 ¿ 1882

Materials and methods

Principles of method if other than guideline:
BUA report
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
2,4-dichloroaniline
EC Number:
209-057-8
EC Name:
2,4-dichloroaniline
Cas Number:
554-00-7
Molecular formula:
C6H5Cl2N
IUPAC Name:
2,4-dichloroaniline

Results and discussion

Any other information on results incl. tables

Biotransformation in soil to higher molecular weight compounds

 

Bordeleau and Bartha, 1972

The authors suggest that the formation of trichloroaniline in soil is catalyzed by peroxidases. In a study two enzymes, a peroxidase and an anilineoxidase, of the fungus Geotrichum candidum L-3, were tested ¿in vitro¿ for their ability to transform dichloroanilines with the help of H2O2 into higher molecular weight compounds. The peroxidase was able to transform 2,4 -, 2,5 - and 3,4-dichloroaniline into their corresponding tetrachloro-azo-compound. The anilineoxidase transformed 2,4-dichloroaniline to 2,2 '4, 4'-tetrachloroazobenzene.

 

Bartha et al., 1968

"Nixon soil" (pH 5.5) was mixed with 1000 mg of 2,4-dichloroaniline/kg soil (dry weight and set to 60% of its field capacity. No tetrachlorobenzene was found after 16 days of incubation at 27 °C. However other unspecified azo-compounds could be identified.

Applicant's summary and conclusion