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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Biodegradation in water: screening tests

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Administrative data

Endpoint:
biodegradation in water: ready biodegradability
Type of information:
read-across from supporting substance (structural analogue or surrogate)
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
data from handbook or collection of data
Justification for type of information:
Dichloroacetyl chloride hydrolyzes very fast (half-life in water is < 1 sec)forming dichloroacetic acid and hydrochloric acid.
Cross-reference
Reason / purpose for cross-reference:
read-across source
Reference
Endpoint:
biodegradation in water: ready biodegradability
Type of information:
experimental study
Adequacy of study:
weight of evidence
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
data from handbook or collection of data
Qualifier:
equivalent or similar to guideline
Guideline:
EU Method C.4-F (Determination of the "Ready" Biodegradability - MITI Test)
GLP compliance:
not specified
Inoculum or test system:
activated sludge (adaptation not specified)
Parameter:
% degradation (O2 consumption)
Value:
97
Sampling time:
15 d
Interpretation of results:
readily biodegradable
Conclusions:
Dichloroacetic acid, present at 100 mg/L, reached 97% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test

Data source

Reference
Title:
NITE; Chemical Risk Information Platform (CHRIP). Biodegradation and Bioconcentration. Tokyo, Japan: Natl Inst Tech Eval. Available from, as of July 24, 2018: https://www.safe.nite.go.jp/english/db.html
Year:
2018
Bibliographic source:
PubChem database

Materials and methods

Test guideline
Qualifier:
equivalent or similar to guideline
Guideline:
EU Method C.4-F (Determination of the "Ready" Biodegradability - MITI Test)
GLP compliance:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
Dichloroacetyl chloride
EC Number:
201-199-9
EC Name:
Dichloroacetyl chloride
Cas Number:
79-36-7
Molecular formula:
C2HCl3O
IUPAC Name:
2,2-dichloroacetyl chloride
Test material form:
liquid

Results and discussion

% Degradation
Parameter:
% degradation (O2 consumption)
Value:
97
Sampling time:
15 d

Applicant's summary and conclusion

Interpretation of results:
readily biodegradable
Conclusions:
Dichloroacetic acid, present at 100 mg/L, reached 97% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test