Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

4.1. Description of first aid measures

Remove contaminated clothing.

If inhaled:

Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.

On skin contact:

Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

On contact with eyes:

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:

Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms

are possible

4.3. Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote

Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media:

water spray, dry powder, foam, carbon dioxide

5.2. Special hazards arising from the substance or mixture

carbon monoxide, Carbon dioxide, toxic gases/vapours, nitrous gases

5.3. Advice for fire-fighters

Special protective equipment:

Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:

Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Avoid inhalation. Avoid contact with the skin, eyes and clothing.

6.2. Environmental precautions

Do not discharge into drains/surface waters/groundwater.

6.3. Methods and material for containment and cleaning up

For large amounts: Pump off product.

For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).

Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.

6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

Precautions for safe handling

Ensure thorough ventilation of stores and work areas. Product should be worked up in closed equipment as far as possible.

7.1. Precautions for safe handling

Ensure thorough ventilation of stores and work areas. Product should be worked up in closed equipment as far as possible.

Protection against fire and explosion:

Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

7.2. Conditions for safe storage, including any incompatibilities

Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated place. Protect against moisture.

Storage stability:

Storage duration: 24 Months

From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

8.1. Control parameters

Components with occupational exposure limits

No occupational exposure limits known.

PNEC

freshwater: 0.10279 mg/l

marine water: 0.010279 mg/l

intermittent release: 1.0279 mg/l

STP: 10 mg/l

sediment (freshwater): 0.46 mg/kg

sediment (marine water): 0.046 mg/kg

soil: 0.0316 mg/kg

oral (secondary poisoning):

No PNEC oral derived, as accumulation in organisms is not to be expected.

DNEL

worker:

Long-term exposure- systemic effects, Inhalation: 0.411 mg/m3

worker:

Long-term exposure- systemic effects, dermal: 0.233 mg/kg

consumer:

Long-term exposure- systemic effects, Inhalation: 0.072 mg/m3

8.2. Exposure controls

Personal protective equipment

Respiratory protection:

Respiratory protection in case of vapour/aerosol release.

Hand protection:

Chemical resistant protective gloves (EN 374)

Suitable materials also with prolonged, direct contact (Recommended:  Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):

butyl rubber (butyl) - 0.7 mm coating thickness

Manufacturer's directions for use should be observed because of great diversity of types.

Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:

Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Body protection:

Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin, eyes and clothing. Wearing of closed work clothing is required additionally to the stated personal protection equipment. The substance was registered as a transported isolated intermediate. The manufacturer/importer has received the confirmation by the user that the substance is used under strictly controlled conditions in accordance with

Art. 18 of the REACH regulation (EC) No 1907/2006. Take off immediately all contaminated clothing. Store work clothing separately.

Stability and reactivity

10.1. Reactivity

No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals:

No corrosive effect on metal.

Formation of flammable gases:       

Remarks:       Forms no flammable gases in the presence of water.

10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions

Reacts with oxidizing agents.

10.4. Conditions to avoid

Avoid extreme temperatures. Avoid humidity.

10.5. Incompatible materials

Substances to avoid:

oxidizing agents

10.6. Hazardous decomposition products

Thermal decomposition products:

carbon oxides, nitrogen oxides

Disposal considerations

13.1. Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.

The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/

authorities.

Contaminated packaging:

Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.

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