Registration Dossier
Registration Dossier
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EC number: 204-539-4 | CAS number: 122-39-4
Guidance on Safe Use
Administrative data
First-aid measures
If inhaled :
Remove to fresh air.
If breathing is labored, administer oxygen.
If breathing has stopped, apply artificial respiration.
Obtain medical attention for any breathing difficulties.
In case of skin contact:
Remove contaminated clothing and shoes.
If on skin, rinse well with water.
Get medical attention immediately if irritation persists.
In case of eye contact:
Immediately flush eye(s) with plenty of water.
If symptoms persist, call a physician.
If swallowed:
Do NOT induce vomiting.
Drink 1 or 2 glasses of water.
Get medical attention immediately.
Never give anything by mouth to an unconscious person.
Most important symptoms and effects, both acute and delayed
Symptoms : The absorption of this product into the body may lead to the formation of methaemoglobine that, in sufficient concentration,
causes cyanosis.
Risks : No information available.
Indication of any immediate medical attention and special treatment needed
Treatment : The first aid procedure should be established in consultation with the doctor responsible for industrial medicine.
Fire-fighting measures
Suitable extinguishing media:
Extinguishing media - large fires
Alcohol-resistant foam
(on small fires)
Carbon dioxide (CO2)
Dry chemical
Water spray
Unsuitable extinguishing media:
Water spray jet
Advice for firefighters
Special protective equipment for firefighters:
Body covering protective clothing, full "turn-out" gear. Self-contained breathing apparatus (EN 133)
Further information:
Do not discharge extinguishing waters into streams, rivers and lakes.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions:
Evacuate unnecessary personnel.
Avoid all contact with material.
Wear suitable protective equipment.
Keep in properly labelled containers.
Dispose of rinse water as waste water.
Environmental precautions:
Toxic to aquatic life.
Avoid release to the environment.
Prevent leaks and prevent soil / water pollution caused by leaks.
Methods for cleaning up:
Shovel up and transfer to suitable, closable containers.
Avoid dust formation.
Do not flush into surface water or sanitary sewer system.
Handling and storage
Advice on safe handling:
Warn personnel about the dangers of the product.
Keep container tightly closed.
Avoid formation of dust and aerosols.
Do not puncture.
Do not get in eyes, on skin, or on clothing.
Provide for appropriate exhaust ventilation and dust collection
at machinery.
Hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product.
Avoid contact with skin, eyes and clothing. Do not breathe dust. Wash thoroughly after handling. Keep working clothes separately.
Wash contaminated clothing before reuse.
Contaminated work clothing should not be allowed out of the workplace.
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Keep containers tightly closed in a dry, cool and wellventilated
place. Protect from moisture.
Advice on common storage:
Never allow product to get in contact with water during storage.
Other data: Stable under normal conditions.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, solid, n.o.s.(diphenylamine)
- Chemical name:
- Diphenylamine
- Language:
- English
- Labels:
- 9
Special provisions / remarks
- Remarks:
- Hazard identification No : 90
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, solid, n.o.s.(diphenylamine)
- Labels:
- 9
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, solid, n.o.s.(diphenylamine)
- Chemical name:
- Diphenylamine
- Labels:
- 9
- Marine pollutant
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3077
Shipping information
- Proper shipping name and description:
- Environmentally hazardous substance, solid, n.o.s. (diphenylamine)
- Chemical name:
- Diphenylamine
- Labels:
- Miscellaneous
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Engineering measures:
Use mechanical ventilation for general area control.
Use local ventilation to keep levels below established threshold values.
Personal protective equipment
Eye protection : Safety glasses with side-shields
Hand protection: Chemical resistant protective gloves
Skin and body protection : Long sleeved clothing
Remove and wash contaminated clothing before re-use.
Change working clothes after each workshift.
Respiratory protection : Breathing apparatus needed only when aerosol or mist is formed.
In the case of dust or aerosol formation use respirator with an approved filter.
Dust safety masks are recommended when the dust concentration is more than 10 mg/m3.
Environmental exposure controls
General advice : Toxic to aquatic life., Avoid release to the environment.,
Prevent leaks and prevent soil / water pollution caused by leaks.
Stability and reactivity
Reactivity
No dangerous reaction known under conditions of normal use.
Chemical stability
Stable under normal conditions.
Possibility of hazardous reactions
Hazardous reactions: Will not occur.
Conditions to avoid
Conditions to avoid: Exposure to air or moisture over prolonged periods.
Incompatible materials
Materials to avoid: Oxidizing agents
Hazardous decomposition products
Hazardous decomposition products:
Carbon monoxide
Carbon dioxide (CO2)
Nitrogen oxides (NOx)
Disposal considerations
Waste treatment methods
Product : Waste must be classified and labelled prior to recycling or disposal.
Dispose of waste product or used containers according to local regulations.
Do not contaminate ponds, waterways or ditches with chemical or used container.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
