A mixture of RR and RS isomers of: (2-(2-methoxy-1-methyl)ethoxy)-1-methylethyl acetate; (2-(2-methoxy-2-methyl)ethoxy)-1-methylethyl acetate; (2-(2-methoxy-2-methyl)ethoxy)-2-methylethyl acetate; (2-(2-methoxy-1-methyl)ethoxy)-2-methylethyl acetate

Guidance on Safe Use

First-aid measures

Eye Contact: Flush eyes thoroughly with water for several minutes.  Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes.  If effects occur, consult a physician, preferably an ophthalmologist.  

Skin Contact: Wash skin with plenty of water.  

Inhalation: Move person to fresh air; if effects occur, consult a physician.  

Ingestion: No emergency medical treatment necessary.  

Notes to Physician: No specific antidote.  Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient.

Fire-fighting measures

Extinguishing Media: Water fog or fine spray.  Dry chemical fire extinguishers.  Carbon dioxide fire extinguishers.  Foam.  Alcohol resistant foams (ATC type) are preferred. General purpose synthetic foams (including AFFF) or protein foams may function, but will be less effective.  

Fire Fighting Procedures: Keep people away.  Isolate fire and deny unnecessary entry.  Stay upwind.  Keep out of low areas where gases (fumes) can accumulate.  Burning liquids may be extinguished by dilution with water.  Do not use direct water stream.  May spread fire.  Eliminate ignition sources.  Burning liquids may be moved by flushing with water to protect personnel and minimize property damage.  

Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves).  If protective equipment is not available or not used, fight fire from a protected location or safe distance.  

Unusual Fire and Explosion Hazards: Violent steam generation or eruption may occur upon application of direct water stream to hot liquids.  Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur.  

Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating.  Combustion products may include and are not limited to:  Carbon monoxide.  Carbon dioxide.

Accidental release measures

Steps to be Taken if Material is Released or Spilled: Small spills:  Absorb with materials such as:  Sand.  Vermiculite.  Collect in suitable and properly labeled containers.  Large spills:  Contain spilled material if possible.  Pump with explosion-proof equipment.  If available, use foam to smother or suppress.  Pump into suitable and properly labeled containers.

Personal Precautions: Isolate area.  Keep unnecessary and unprotected personnel from entering the area.  Keep personnel out of low areas.  No smoking in area.  Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion.  Vapor explosion hazard.  Keep out of sewers.  Use appropriate safety equipment.  

Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater.

Handling and storage

General Handling: No smoking, open flames or sources of ignition in handling and storage area.  Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur.  Electrically ground and bond all equipment.  Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers.  Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation.  Spills of these organic materials on hot fibrous insulations may lead to lowering of the autoignition temperatures possibly resulting in spontaneous combustion.

Storage: Minimize sources of ignition, such as static build-up, heat, spark or flame.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

Not regulated according to the transport regulation.

Shipping information

Proper shipping name and description:

Not applicable.

Chemical name:

Not applicable.

Language:

English

Labels:

Not applicable.

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

Shipping information

Proper shipping name and description:

NOT REGULATED

Chemical name:

Not applicable

Language:

English

Labels:

Not applicable.

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

Not regulated according to the transport regulation.

Shipping information

Proper shipping name and description:

NOT REGULATED

Chemical name:

Not applicable.

Labels:

Not applicable.

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

Not regulated according to the transport regulation.

Shipping information

Proper shipping name and description:

Not applicable.

Chemical name:

Not applicable.

Labels:

Not applicable.

Remarks

Additional transport information

Additional information

Special provisions / remarks / other:

Not applicable

Exposure controls / personal protection

Personal Protection

Eye/Face Protection: Use safety glasses.  Safety glasses should be consistent with EN 166 or equivalent.  

Skin Protection: When prolonged or frequently repeated contact could occur, use protective clothing chemically resistant to this material. Selection of specific items such as faceshield, boots, apron, or full-body suit will depend on the task.  Remove contaminated clothing immediately, wash skin area with soap and water, and launder clothing before reuse or dispose of properly.

Hand protection: Use gloves chemically resistant to this material when prolonged or frequently repeated contact could occur.  Use chemical resistant gloves classified under Standard EN374: Protective gloves against chemicals and micro-organisms.  Examples of preferred glove barrier materials include:  Butyl rubber.  Polyethylene.  Chlorinated polyethylene.  Ethyl vinyl alcohol laminate ("EVAL").  Examples of acceptable glove barrier materials include:  Viton.  Natural rubber ("latex").  Polyvinyl chloride ("PVC" or "vinyl").  Nitrile/butadiene rubber ("nitrile" or "NBR").  When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended.  When only brief contact is expected, a glove with a protection class of 1 or higher (breakthrough time greater than 10 minutes according to EN 374) is recommended.  NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier.

Respiratory Protection: No respiratory protection should be needed.    

Ingestion: Use good personal hygiene.  Do not consume or store food in the work area.  Wash hands before smoking or eating.

Stability and reactivity

Stability/Instability: Stable under recommended storage conditions.

Conditions to Avoid: Product can oxidize at elevated temperatures.  Avoid static discharge.  Flammable vapors can be released at elevated temperatures.

Incompatible Materials: Avoid contact with oxidizing materials.  Avoid contact with:  Strong acids.  Strong oxidizers.  

Hazardous Polymerization: Will not occur.  

Thermal Decomposition: Decomposition products depend upon temperature, air supply and the presence of other materials.

Disposal considerations

Any disposal practice must be in compliance with all local and national laws and regulations.  Do not dump into any sewers, on the ground, or into any body of water.