Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
General information
If the patient is likely to become unconscious, place and transport in stable sideways position. Remove contaminated clothing immediately and dispose of safely.
After inhalation
When inhaled remove to fresh air and seek medical aid.
After skin contact
Wash immediately with plenty of water for several minutes. Seek medical attention.
After eye contact
Remove contact lenses, irrigate copiously with clean, fresh water for at least 15 minutes, holding the eyelids apart and seek medical advice.
After ingestion
Do not induce vomiting. Let plenty of water be drunk in small gulps. Call a doctor immediately.
Most important symptoms and effects, both acute and delayed
No data available.
Indication of any immediate medical attention and special treatment needed
No data available.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media
No data available.
Unsuitable extinguishing media
High power water jet
Special hazards arising from the substance or mixture
In the event of fire, the following can be released: Metal oxides; fluorine compounds
Advice for firefighters
Use self-contained breathing apparatus. Wear protective clothing.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency personnel
Ensure adequate ventilation. Keep people away and stay on the upwind side. Refer to protective measures listed in sections Handling and storage and Exposure controls/personal protection.
For emergency responders
No data available. Personal protective equipment (PPE) - see Section Exposure controls/personal protection.
Environmental precautions
Do not discharge into the drains/surface waters/groundwater. Do not discharge into the subsoil/soil.
Methods and material for containment and cleaning up
Take up mechanically. When picked up, treat material as prescribed under heading "Disposal considerations". Ensure adequate ventilation.
Reference to other sections
Information regarding waste disposal, see chapter Disposal considerations.

Handling and storage

Precautions for safe handling
Advice on safe handling
Product inherent handling risks must be minimised taking the appropriate measures for protection and preventive actions. The working process should be designed to rule out the release of hazardous substances or skin contact as far it is possible by the state of the art. Open and handle container with care. Avoid eye, skin and clothing contact. Do not inhale dust.
General protective and hygiene measures
Wash hands before breaks and after work. Keep away from food, drink and animal feeding stuffs. Remove soiled or soaked clothing immediately. Avoid contact with eyes and skin. Provide eye wash fountain in work area. Do not eat, drink or smoke during work time. Do not inhale dust/fumes/aerosols. Have emergency shower available.
Advice on protection against fire and explosion
Keep away from sources of ignition - refrain from smoking.
Conditions for safe storage, including any incompatibilities
Technical measures and storage conditions
Keep only in the original container, tightly closed, in a well ventilated place. Keep under lock and key or accessible only to specialists or people who are authorized. Protect from atmospheric moisture and water.
Requirements for storage rooms and vessels
Containers which are opened must be carefully closed and kept upright to prevent leakage. Protect from heat and direct sunlight.
Specific end use(s)
No data available.

Transport information

Land transport (ADR/RID)

UN number:
UN2923
Shippingopen allclose all
Class:
8
Classification code:
CT2
Packaging group:
I
Labels:
8+6.1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN2923
Shippingopen allclose all
Class:
8
Classification code:
CT2
Packaging group:
I
Labels:
8+6.1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN2923
Proper shipping name and description:
CORROSIVE SOLID, TOXIC, N.O.S
Chemical name:
zinc-hexafluorosilicate
Class:
8
Packaging group:
I
EmS code:
F-A, S-B
Labels:
8+6.1
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN2923
Proper shipping name and description:
Corrosive solid, toxic, n.o.s.
Chemical name:
zinc-hexafluorosilicate
Class:
8
Packaging group:
I
Labels:
8+6.1
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure controls
Appropriate engineering controls
No data available.
Personal protective equipment
Respiratory protection
If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. In case of aerosol and mist formation, take appropriate measures for breathing protection in the event workplace threshold values are not specified.
Eye / face protection
Tightly fitting safety glasses (EN 166).
Hand protection
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the product . Before use, the protective gloves should be tested in any case for its specific work-station suitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoid permanent use of protective gloves.
Other
Normal chemical work clothing.
Environmental exposure controls
No data available.

Stability and reactivity

Reactivity
Dangerous reactions are not expected if the product is handled according to its intended use.
Chemical stability
Stable under recommended storage and handling conditions (See section 7).
Possibility of hazardous reactions
Stable under recommended storage and handling conditions (See section 7).
Conditions to avoid
Moisture. Heat
Incompatible materials
No data available.
Hazardous decomposition products
None if stored, handled and transported properly.

Disposal considerations

Waste treatment methods
Product
Allocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreement with the regional waste disposal company.
Packaging
Residuals must be removed from packaging and when emptied completely disposed of in accordance with the regulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specified by the regional disposer.