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Administrative data

Endpoint:
flammable solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2017-03-03 to 2018-01-18
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2017

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
UN Manual of Tests and Criteria: Test N.1 (Test method for readily combustible solids)
Deviations:
no
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
Trihydrogen [29H,31H-phthalocyaninetrisulphonato(5-)-N29,N30,N31,N32]cuprate(3-), compound with N,N'-di(o-tolyl)guanidine (1:3)
EC Number:
277-086-3
EC Name:
Trihydrogen [29H,31H-phthalocyaninetrisulphonato(5-)-N29,N30,N31,N32]cuprate(3-), compound with N,N'-di(o-tolyl)guanidine (1:3)
Cas Number:
72928-60-0
Molecular formula:
C32H16-τN8Cu(SO3C15H18N3)τ
IUPAC Name:
Bis and tris and tetra [N-(2-methylanilino)-N’-(2-methylanilino) methaniminium][phthalocyaninesulfonato-κ4N29,N30,N31,N32]cuprate(II)
Test material form:
solid: particulate/powder
Specific details on test material used for the study:
STORAGE CONDITIONS OF TEST MATERIAL
- Storage condition of test material: in darkness at room temperature

TREATMENT OF TEST MATERIAL PRIOR TO TESTING
- Treatment of test material prior to testing: none

Results and discussion

Flammable solids
Key result
Test procedure:
burning rate test: preliminary screening test
Burning time:
> 2 min
Remarks on result:
substance does not ignite and propagate combustion either by burning with flame or smouldering along 200 mm of the powder train within the 2 minutes test period

Any other information on results incl. tables

Preliminary test

Assay No. 1

The test item burnt and became black. No propagation of the combustion was observed.

Assay No. 2

The same observations as for the assay No. 1 were recorded

Main test

Taking into account the results obtained during the preliminary test, no main test was performed.

Applicant's summary and conclusion

Interpretation of results:
not classified based on GHS criteria
Conclusions:
The test item was not classified as a flammable solid of Division 4.1 and thus was not assigned to any packing group, under the experimental conditions used.
According to EC No. 1272/2008 (CLP), the test item was not classified.
Executive summary:

The test was performed according to the United Nations Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria - Sixth revised edition (2015) Method N.4 (Part III, Section 33.3.1.6) EC No. 1272/2008 (CLP).

No self ignition of the test item was recorded. The result is considered negative, the test item was not classified in division 4.2.

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