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Physical & Chemical properties

Boiling point

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Administrative data

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Reference
Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
key study
Study period:
1 October 2018 to 14 March 2019
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 103 (Boiling Point)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.2 (Boiling Temperature)
Deviations:
no
GLP compliance:
yes
Type of method:
differential scanning calorimetry
Specific details on test material used for the study:
Purity: 100% (UVCB)
Appearance/Physical state: Solid, white pastille
Storage: Room temperature in the dark
Key result
Boiling pt.:
> 195 °C
Atm. press.:
101.6 kPa
Decomposition:
yes
Decomp. temp.:
ca. 195 °C

The left limit of the small endotherm observed at approximately 200 deg. C onwards in the thermal analysis has been considered as the onset of decomposition noted in the modified liquid bath test.

As a result of the low rate of enthalpy change and color change during decomposition, the onset temperature could only be approximated.

Similar thermographic profiles were obtained using air and nitrogen atmospheres, which indicates that the observed decomposition is probably thermal and not oxidative.

Conclusions:
In a study conducted according to OECD 103, using differential scanning calorimetry, the test item was determined to decompose from 195 deg.C at 101.6 kPa. As the test item decomposed, no value for boiling point could be determined.
Executive summary:

The test item decomposed from approximately 195 deg. C at 101.6 kPa, by differential scanning calorimetry and using a modified liquid bath method, designed to be compatible with Method A.2 Boiling Temperature of Commission Regulation (EC) No 440/2008 of 30 May 2008, and OECD Guidelines for Testing of Chemicals No. 103, 27 July 1995. As the test item decomposed, no value for boiling point could be determined.

Description of key information

In a study conducted according to OECD 103, using differential scanning calorimetry, the test item was determined to decompose from 195 deg. C at 101.6 kPa.  As the test item decomposed, no value for boiling point could be determined.

Key value for chemical safety assessment

Additional information