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Reaction mass of [(2S,3R,4S,5S,6R)-6-[[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl] (1S,2R,4aS,6aR,6aR,6bR,8R,8aR,9R,10R,11R,12aR,14bS)-8,10,11-trihydroxy-9-(hydroxymethyl)-1,2,6a,6b,9,12a-hexamethyl-2,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydro-1H-picene-4a-carboxylate and [(2S,3R,4S,5S,6R)-6-[[(2R,3R,4R,5S,6R)-3,4-dihydroxy-6-(hydroxymethyl)-5-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl] (4aS,6aR,6aS,6bR,8R,8aR,9R,10R,11R,12aR,14bS)-8,10,11-trihydroxy-9-(hydroxymethyl)-2,2,6a,6b,9,12a-hexamethyl-1,3,4,5,6,6a,7,8,8a,10,11,12,13,14b-tetradecahydropicene-4a-carboxylate
EC number: 953-451-9 | CAS number: -
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Endpoint summary
Administrative data
Description of key information
Key value for chemical safety assessment
Skin irritation / corrosion
Link to relevant study records
- Endpoint:
- skin irritation: in vivo
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 2002-06-08 to 2002-09-08
- Reliability:
- 1 (reliable without restriction)
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 404 (Acute Dermal Irritation / Corrosion)
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
- Species:
- rabbit
- Strain:
- New Zealand White
- Details on test animals or test system and environmental conditions:
- 3 male albinos rabbits, numerated A4789, A4790 and A4791 of new-zealand strain, originating from the Elevage de Gérome (Quartier Labaste – 40260 Linxe) were kept during a 7-day acclimatisation period.
During the test, the animals weighted between 2.23kg and 2.31kg.
The animals were kept in individual boxes installed in conventional air conditioned animal husbanding.
The environmental conditions were:
- temperature: between 19 °C and 22 °C
- relative humidity: between 47% and 52% - Type of coverage:
- semiocclusive
- Preparation of test site:
- shaved
- Vehicle:
- water
- Controls:
- yes
- Amount / concentration applied:
- The product MADECASSOSIDE was applied, as supplied, at the dose of 0.5g, under semi-occlusive dressing.
- Duration of treatment / exposure:
- 4 hours
- Observation period:
- The skin reactions were appreciated 1 hour and then 24, 48 and 72 hours after removal of the patch.
- Number of animals:
- 3
- Irritation parameter:
- edema score
- Basis:
- mean
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Irritation parameter:
- erythema score
- Basis:
- mean
- Time point:
- 24/48/72 h
- Score:
- >= 0 - <= 1
- Max. score:
- 1
- Irritant / corrosive response data:
- Primary skin irritation: PSi = 0.2
1 hour after removal of the patch: 0/3 animals with skin reaction
24 hours after removal of the patch: 1/3 animals with skin reaction (slight erythema)
72 hours after removal of the patch: 0/3 animals with skin reaction - Interpretation of results:
- other: not classified
- Conclusions:
- The results obtained, in these experimental conditions, enabled to conclude that the test product MADECASSOSIDE, according to the scales of interpretation retained:
- is non irritant to skin (PSi =0.2) according to the classification established in the Journal Officiel
de la République Française dated February 21st, 1982, - and, must not be classified, according to the criteria for classification, packaging and labelling of
dangerous substances in compliance with the E.E.C. Directives 67/548 and 99/45. - Executive summary:
The product MADECASSOSIDE was applied, as supplied, at the dose of 0.5g, under semi-occlusive dressing during 4 hours on an undamaged skin area of 3 rabbits, according to an experimental protocol established from the O.E.C.D. guideline (n° 404 dated July 17th, 1992) and the method B.4 of the E.E.C. directive n° 92/69 dated December 29th,1992.
It was only noted a slight erythema, in 1 animal on the reading time 24 hours.
The results obtained, in these experimental conditions, enabled to conclude that the test product MADECASSOSIDE, according to the scales of interpretation retained:
- is non irritant to skin (PSi = 0.2) according to the classification established in the Journal Officiel de la République Française dated February 21st, 1982,
- and, must not be classified, according to the criteria for classification, packaging and labelling of dangerous substances in compliance with the E.E.C. Directives 67/548 and 96/45.
Reference
The product MADECASSOSIDE was applied, as supplied, at the dose of 0.5g, under semi-occlusive dressing during 4 hours on an undamaged skin area of 3 rabbits, according to an experimental protocol established from the O.E.C.D. guideline (n° 404 dated July 17th, 1992) and the method B.4 of the E.E.C. directive n° 92/69 dated December 29th,1992.
It was only noted a slight erythema, in 1 animal on the reading time 24 hours.
The results obtained, in these experimental conditions, enabled to conclude that the test product MADECASSOSIDE, according to the scales of interpretation retained:
- is non irritant to skin (PSi = 0.2) according to the classification established in the Journal Officiel de la République Française dated February 21st, 1982,
- and, must not be classified, according to the criteria for classification, packaging and labelling of dangerous substances in compliance with the E.E.C. Directives 67/548 and 96/45.
Endpoint conclusion
- Endpoint conclusion:
- no adverse effect observed (not irritating)
Eye irritation
Link to relevant study records
- Endpoint:
- eye irritation: in vivo
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 2002-08-11 to 2002-18-14
- Reliability:
- 1 (reliable without restriction)
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 405 (Acute Eye Irritation / Corrosion)
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
- Species:
- rabbit
- Strain:
- New Zealand White
- Details on test animals or tissues and environmental conditions:
- Three female albinos rabbits of New Zealand strain, numbered A4825, A4826 and A4827, originating from the Elevage de Gérome (Quartier Labaste – F40260 Linxe) were kept during a 5 day acclimatisation period. During the test, the animals weighed between 2.20kg and 2.37kg.
Animals were kept in individuals boxes, the environmental conditions were:
- temperature: between 19 °C and 21 °C
- relative humidity: between 45% and 52% - Vehicle:
- unchanged (no vehicle)
- Controls:
- yes
- Amount / concentration applied:
- A quantity of 0.1 g of the pure test product was instilled into one eye of each rabbit
- Number of animals or in vitro replicates:
- 3
- Details on study design:
- Ocular examinations were performed on both right and left eyes 1 hour after instillation and 24, 48 and72 hours later.
- Irritation parameter:
- chemosis score
- Basis:
- mean
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- fully reversible
- Irritation parameter:
- conjunctivae score
- Basis:
- mean
- Time point:
- 24/48/72 h
- Score:
- ca. 0.7
- Max. score:
- 1
- Reversibility:
- fully reversible
- Irritation parameter:
- iris score
- Basis:
- mean
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- fully reversible
- Irritation parameter:
- cornea opacity score
- Basis:
- mean
- Time point:
- 24/48/72 h
- Score:
- 0
- Max. score:
- 0
- Reversibility:
- fully reversible
- Irritant / corrosive response data:
- The ocular reactions observed during the study remained slight and only recorded at the conjunctivae level: very slight redness in the 3 animals on examinations times 1, 24 and 48 hours associated with a very slight chemosis in 2 animals only at the reading time 1 hour.
- Interpretation of results:
- other: not classified
- Conclusions:
- The result obtained, in these experimental conditions, enable to conclude that the test product MADECASSOSIDE:
- is slightly irritant for the eye (Max. O.I = 9.3) according to the classification established in the Journal Officiel de la République Française dated July 10th, 1992.
- and, must not be classified according to the criteria for the classification, packaging and labelling of dangerous substances in compliance with the E.E.C. Directive n° 67/548 and 99/45. - Executive summary:
The product MADECASSOSIDE was instilled, as supplied, into the eye of three New Zealand rabbits at the dose of 0.1 g, according to the experimental protocol established on the basis of the official method as defined in the O.E.C.D. guideline n° 405 dated February 24th, 1987 and the test method B.5 of the E.E.C. directive n° 92/69 dated December 29th, 1992.
The ocular reactions observed during the study remained slight and only recorded at the conjunctivae level: very slight redness in the 3 animals on examinations times 1, 24 and 48 hours associated with a very slight chemosis in 2 animals only at the reading time 1 hour.
In conclusion, the result obtained, in these experimental conditions, enable to conclude that the test product MADECASSOSIDE:
- is slightly irritant for the eye (Max. O.I = 9.3) according to the classification established in the
Journal Officiel de la République Française dated July 10th, 1992.
- and, must not be classified according to the criteria for the classification, packaging and labelling of dangerous substances in compliance with the E.E.C. Directive n° 67/548 and 99/45.
Reference
The result obtained, in these experimental conditions, enable to conclude that the test product MADECASSOSIDE:
- is slightly irritant for the eye (Max. O.I = 9.3) according to the classification established in the Journal Officiel de la République Française dated July 10th, 1992.
- and, must not be classified according to the criteria for the classification, packaging and labelling of dangerous substances in compliance with the E.E.C. Directive n° 67/548 and 99/45.
NOTE :
If no reaction is observed at 72 hours (D3) after instillation, the study is finished. In case of persistent reactions, additional observations can be carried out at Day 4 (D4), to Day 21 (D21) in order to determine the reversible character of the lesions observed.
Endpoint conclusion
- Endpoint conclusion:
- no adverse effect observed (not irritating)
Additional information
Justification for classification or non-classification
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