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Diss Factsheets

Physical & Chemical properties

Oxidising properties

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Endpoint:
oxidising solids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
from 1999-07-06 to 1999-07-13
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.17 (Oxidising Properties (Solids))
Deviations:
no
GLP compliance:
yes
Contact with:
powdered cellulose
Sample tested:
reference mixture as specified
Remarks:
60 % Bariumnitrat and 40 % Cellulose
Parameter:
burning rate
Result:
1.1 mm/s
Key result
Sample tested:
4:1 sample-to-cellulose ratio
Parameter:
burning rate
Remarks on result:
mixture does not ignite and burn
Key result
Sample tested:
1:1 sample-to-cellulose ratio
Parameter:
burning rate
Remarks on result:
mixture does not ignite and burn

The reference mixture was a mixture of 60 % Bariumnitrat and 40 % Cellulose. It burned with a speed rate of 1,1 mm/s. Following the singular results:


 














































Mixture



Burning distance / Burning time / Buring speed rate



10 % Substance / 90 % Cellulose



The amount extinguished within the start segment



20 % Substance / 80 % Cellulose



The amount extinguished within the start segment



30 % Substance / 70 % Cellulose



The amount extinguished within the start segment



40 % Substance / 60 % Cellulose



The amount extinguished within the start segment



50 % Substance / 50 % Cellulose



The amount extinguished within the start segment



60 % Substance / 40 % Cellulose



The amount extinguished within the start segment



70 % Substance / 30 % Cellulose



The amount extinguished within the start segment



80 % Substance / 20 % Cellulose



The molten mass was not ignitable



90 % Substance / 10 % Cellulose



The molten mass was not ignitable



 


The test item has no oxidizing properties when tested according to this procedure.

Interpretation of results:
GHS criteria not met
Conclusions:
The test item has no oxidizing properties under the test conditions.
Executive summary:

An experimental study was conducted according to EU Method A.17. to determine the oxidizing properties of the test item. The test item was mixed with Cellulose in different ratios (10 - 90 %). None of the investigated mixtures with Cellulose did burn. Due to the test results the test item does not have to be classified as oxidizing solid.

Endpoint:
oxidising liquids
Data waiving:
study technically not feasible
Justification for data waiving:
the study does not need to be conducted because the substance is a solid
Endpoint:
oxidising gases
Data waiving:
study technically not feasible
Justification for data waiving:
the study does not need to be conducted because the substance is a solid

Description of key information

The test item has no oxidizing properties.

Key value for chemical safety assessment

Oxidising properties:
non oxidising

Additional information

Oxidising gases


The test item is a solid at ambient conditions. This hazard class is only applicable for gases. Thus, the substance was not considered for classification as oxidising gases.


 


Oxidising liquids


The test item is a solid at ambient conditions. This hazard class is only applicable for gases. Thus, the substance was not considered for classification as oxidising liquids.


 


Oxidising solids


An experimental study was conducted according to EU Method A.17. to determine the oxidizing properties of the test item. The test item was mixed with Cellulose in different ratios (10 - 90 %). None of the investigated mixtures with Cellulose did burn. Due to the test results the test item does not have to be classified as oxidizing solid.

Justification for classification or non-classification

Classification, Labelling, and Packaging Regulation (EC) No 1272/2008


Based on the chemical structure and taking into account the provisions laid down in Regulation (EC) No 1272/2008 (CLP), as amended for the seventeenth time in Regulation (EU) 2021/849, and UN GHS Rev 9 (2021) the substance is not considered to be classified as oxidising gas, oxidising liquid or oxidising solid in class 5 Division 5.1.