Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

Description of first aid measures

Take off all contaminated clothing immediately.


If aerosol or mists are formed:

Move victims into fresh air.

In case of persistent discomfort: Consult doctor immediately.

Skin contact

Wash off immediately with plenty of water.

Consult a doctor in the event of permanent skin irritation.

Eye contact

Keeping eyelid open, immediately rinse thoroughly for at least 5 minutes using plenty of water or, if necessary, eye rinsing solution.

In case of persistent discomfort: Consult an ophthalmologist.


Have the mouth rinsed with water.

Consult a physician immediately.

Indication of any immediate medical attention and special treatment needed

If required, therapy of irritative effect.

After absorbing large amounts of substance:

Liberation of reaction products (Methanol) can lead to symptoms of poisoning.

Possible signs of poisoning:

daze, dizziness, nausea, colicky abdominal pain, respiratory disturbance.

Symptoms upon increasing intoxication: dysopia, loss of eyesight.


Immediate gastric lavage. Antidote treatment, correction of acid-base balance.

Detection of substance (Methanol) possible in:


Antidote treatment: ethanol.

Fire-fighting measures

Suitable extinguishing media

Water spray, foam, CO2, dry powder.

Unsuitable extinguishing media

high volume water jet

Special protective equipment for fire-fighters

In case of fire: wear a self contained respiratory apparatus

Advice for firefighters

Water used to extinguish fire should not enter drainage systems, soil or stretches of water.

Ensure there are sufficient retaining facilities for water used to extinguish fire.

Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment.

Ensure adequate ventilation.

Environmental precautions

Do not allow entrance in sewage water, soil stretches of water, groundwater, drainage systems.

Methods and material for containment and cleaning up

Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).

Fill into marked, sealable containers.

To be disposed of in compliance with existing regulations.

Suitable binder:       universal absorbent, sawdust, sand (for damming up)

Handling and storage


Precautions for safe handling

Provide good ventilation or extraction.

Advice on protection against fire and explosion

Normal measures for preventive fire protection.

Keep away from sources of ignition - No smoking.


Conditions for safe storage, including any incompatibilities

Keep containers tightly closed in a cool, well-ventilated place.

Protect from moisture.

Transport information

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Marine transport (UN RTDG/IMDG)

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Additional transport information

Additional information
Special provisions / remarks / other:
Not classified as dangerous in the meaning of transport regulations.

Exposure controls / personal protection

•       Methanol

CAS-No.       67-56-1       EC-No.


Control parameters       200 ppm

266 mg/m3              Time Weighted Average (TWA):(EH40 WEL)

Control parameters                     Skin designation:(EU ELV)

      Can be absorbed through the skin.

Engineering measures

Provide good ventilation or extraction.

Personal protective equipment

Respiratory protection

In case of dusts/vapours/aerosols being formed or if the limit values like TLV are exceeded:

use respiratory equipment with suitable filter (filter type ABEK) or wear a self contained respiratory apparatus

Use only respiratory protection equipment with CE-symbol including four digit test number.

The filter class for the respirator must be suitable for the maximum expected contaminant concentration (gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, self-contained breathing apparatus must be used.

Note time limit for wearing respiratory protective equipment.

Hand protection

Glove material       for example, butyl-rubber

Material thickness       0.5 mm

Break through time       >= 480 min

Glove material       for example, Fluorinated rubber (Viton)

Material thickness       0.4 mm

Break through time       >= 480 min

Selection of protective gloves to meet the requirements of specific workplaces.

Suitability for specific workplaces should be clarified with protective glove manufacturers.

The information is based on our own tests, references from the literature and information from glove manufacturers, or derived by analogy with similar materials.

Remember that the useful time per day of a chemical protection glove may be much shorter than the permeation time determined according to EN 374 due to the many different influential factors involved (e.g. temperature).

Eye protection

safety glasses

Stability and reactivity

Hazardous decomposition products:

Methanol in case of hydrolysis.

Further information:       

Incompatibility with:

atmospheric humidity




Disposal considerations


With respect to local regulations, e.g. dispose of to suitable waste incineration plant.

Uncleaned packaging

Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.

If there is product residue in the emptied container, follow directions for handling on the container's label.

Incorrect disposal or reuse of this container is illegal and can be dangerous.

Other countries: observe the national regulations.

Waste Key Number

No waste key number as per the European Waste Types List can be assigned to this product, since such classification is based on the (as yet undetermined) use to which the product is put by the consumer.

The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.