Registration Dossier
Registration Dossier
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EC number: 435-410-2 | CAS number: 351491-23-1
Guidance on Safe Use
Administrative data
First-aid measures
General advice
- Show this safety data sheet to the doctor in attendance.
- First aider needs to protect himself.
- Place affected clothing in a sealed bag for subsequent decontamination.
In case of inhalation
- Move to fresh air.
- Keep at rest.
- Consult a physician if necessary.
In case of skin contact
- Take off contaminated clothing and shoes immediately.
- Wash off with soap and plenty of water.
- Wash immediately and thoroughly for a prolonged period (at least 15 minutes).
- Consult a physician if necessary.
In case of eye contact
- Rinse with running water whilst keeping the eyes wide open (at least 15 minutes)
In case of ingestion
- Do NOT induce vomiting.
- Do not give anything to drink.
- Consult a physician if necessary.
Fire-fighting measures
Suitable extinguishing media
- Water spray
- Foam
- Carbon dioxide (CO2)
- Multi-purpose powders
Unsuitable extinguishing media
- High volume water jet
Special protective equipment for firefighters
- In the event of fire, wear self-contained breathing apparatus.
- Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing
Specific fire fighting methods
- Do not use a solid water stream as it may scatter and spread fire.
Further information
- Standard procedure for chemical fires.
- Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
- Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.
Accidental release measures
Wear suitable protective equipment.
- Personal protective equipment
- Wear suitable gloves.
- Avoid contact with the skin and the eyes.
- Tightly fitting safety goggles
- Remove all sources of ignition.
- Stop the leak. Turn leaking containers leak-side up to prevent the escape of liquid.
- Only qualified personnel equipped with suitable protective equipment may intervene.
- Ventilate the area.
Dam up.
- Prevent product from entering sewage system.
- Contain the spilled material by bunding
Recovery
- Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations (see section 13).
- Keep in suitable, closed containers for disposal.
- Keep in properly labelled containers.
- Use approved industrial vacuum cleaner for removal.
Decontamination/cleaning
- Wash off with plenty of water.
- Clean contaminated surface thoroughly.
- Recover the cleaning water for subsequent disposal.
Disposal
- Dispose of in accordance with local regulations.
Handling and storage
- Handle in accordance with good industrial hygiene and safety practice.
- Do NOT handle without gloves.
- Avoid the formation or spread of mists in the atmosphere.
- Provide adequate ventilation.
- Does not require any specific or particular measures
Take all necessary measures to avoid accidental discharge of products into drains and waterways due to the rupture of containers or transfer systems.
- Stable under normal conditions.
- Keep container tightly closed in a dry and well-ventilated place.
- Keep away from heat and source of ignition
Recommended storage temperature: <= 30 °C
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 1993
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Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 1993
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Marine transport (UN RTDG/IMDG)
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, N.O.S. (2-mercaptopropionic acid, methyl ester, o-ethyl dithiocarbonate)
- Chemical name:
- liquid halogenated hydrocarbons
- Labels:
- 3
- Marine pollutant
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Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 1993
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, N.O.S. (2-mercaptopropionic acid, methyl ester, o-ethyl dithiocarbonate)
- Chemical name:
- 2-mercaptopropionic acid, methyl ester, o-ethyl dithiocarbonate
- Labels:
- 3
Remarksopen allclose all
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Exposure controls / personal protection
Heptane : TWA = 500 ppm (2.085 mg/m3) Europe
Engineering measures
- Extract at emission point.
- Avoid splashes.
- Apply technical measures to comply with the occupational exposure limits.
- Facilities and equipment easily cleanable.
- Provide adequate ventilation.
Individual protection measures
Respiratory protection
- Use a respirator with an approved filter if a risk assessment indicates this is necessary.
Hand protection
- Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
- Neoprene gloves
- Where there is a risk of contact with hands, use appropriate gloves
- Gloves must be inspected prior to use.
- Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
- The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Suitable material
- Rubber gloves
Eye protection
- Wear safety glasses with side shields or goggles.
Skin and body protection
- Full protective suit
- Disposable impermeable suit
- Rubber boots.
- Rubber apron
- Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Stability and reactivity
- Stable under recommended storage conditions.
- Hazardous polymerisation does not occur
Conditions to avoid
- Keep away from heat and sources of ignition.
- Keep away from flames and sparks.
Incompatible materials:
- Strong oxidizing agents
- Acids
- Alkalis and caustic products.
Hazardous decomposition products:
- On combustion or on thermal decomposition (pyrolysis) releases:
- (Carbon oxides (CO + CO2)).
- Sulphur compounds
- Chlorinated compounds
Disposal considerations
Product Disposal
- Dispose of as hazardous waste in compliance with local and national regulations.
- Dispose of wastes in an approved waste disposal facility.
- Dispose of in accordance with local regulations.
- Completely empty the packaging prior to decontamination.
- Carefully drain and then steam clean.
- The user's attention is drawn to the possible existence of local regulations regarding disposal.
Advice on cleaning and disposal of packaging
- Avoid release to the environment.
- In accordance with RID/ADR regulations containers or tankers, which have not been cleaned or deodorized and which previously contained a hazardous product, must either be labelled or have hazard signs.
- in crystallised form
Measure for waste avoidance or recovery
- Do not dispose of the product at a rubbish tip.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
