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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Hydrolysis

Currently viewing:

Administrative data

Endpoint:
hydrolysis
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Report date:
1987

Materials and methods

Test guidelineopen allclose all
Qualifier:
equivalent or similar to guideline
Guideline:
OECD Guideline 111 (Hydrolysis as a Function of pH)
Qualifier:
equivalent or similar to guideline
Guideline:
EU Method C.7 (Degradation: Abiotic Degradation: Hydrolysis as a Function of pH)
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
Chlorosulphonyl isocyanate
EC Number:
214-715-2
EC Name:
Chlorosulphonyl isocyanate
Cas Number:
1189-71-5
Molecular formula:
CClNO3S
IUPAC Name:
[(chlorosulfonyl)imino]methanone
Test material form:
gas under pressure: refrigerated liquefied gas
Details on test material:
- Name of test material: Chlorosulfonyl isocyanate
Radiolabelling:
no

Study design

Analytical monitoring:
yes
Estimation method (if used):
Quantitative analysis of chloride ions by spectroscopy.
Duration of test
Duration:
24 h
Temp.:
25
Initial conc. measured:
ca. 2 mg/L

Results and discussion

Transformation products:
yes
Identity of transformation productsopen allclose all
No.:
#1
Reference
Reference substance name:
Unnamed
IUPAC name:
sulfamic acid
Inventory number:
InventoryMultipleMappingImpl [inventoryEntryValue=EC 226-218-8]
CAS number:
5329-14-6
No.:
#2
Reference
Reference substance name:
Unnamed
IUPAC name:
chloride
Inventory number:
InventoryMultipleMappingImpl [inventoryEntryValue=EC 231-595-7]
CAS number:
7647-01-0
No.:
#3
Reference
Reference substance name:
Unnamed
IUPAC name:
dioxomethane
Inventory number:
InventoryMultipleMappingImpl [inventoryEntryValue=EC 204-696-9]
CAS number:
124-38-9
Total recovery of test substance (in %)
% Recovery:
>= 89.2 - <= 110
Temp.:
25
Duration:
>= 2 - <= 24 h
Dissipation DT50 of parent compound
Temp.:
25 °C
DT50:
ca. 0 h
Type:
(pseudo-)first order (= half-life)

Applicant's summary and conclusion

Validity criteria fulfilled:
yes
Conclusions:
Most of the test substance was hydrolyzed rapidly upon contacted with water, and complete hydrolysis was observed after 24 hours.
Executive summary:

A study was carried out similar or equivalent to OECD Guideline 111 and EU Method C.7 (Degradation: Abiotic Degradation: Hydrolysis as a Function of pH). Most of the test substance was hydrolyzed rapidly upon contacted with water, and complete hydrolysis was observed after 24 hours.