Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-flammability
Type of information:
migrated information: read-across from supporting substance (structural analogue or surrogate)
Adequacy of study:
supporting study
Study period:
Between 05 April and 18 April 2012.
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
other: Cited from ECHA disseminated dossier Query date: 2015-07-22 For justification of read across please refer to IUCLID section 13.

Data source

Reference
Reference Type:
other: ECHA disseminated dossier
Title:
No information
Report date:
2015

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes

Test material

Constituent 1
Reference substance name:
939-183-5
EC Number:
939-183-5
IUPAC Name:
939-183-5
Details on test material:
Identification: ERC#18
Description: clear colorless liquid
Batch: 9114460/002
Purity: 100 % (UVCB)
Expiry / Retest Date: 23 January 2013
Storage Conditions: room temperature in the dark

Results and discussion

Auto-ignition temperature (liquids / gases)
Auto-ignition temperature:
238 °C
Atm. press.:
98.1 - 98.8 kPa
Remarks on result:
other:

Any other information on results incl. tables

Results

Results of the auto-ignition temperature determination are shown in the following table.

 

Table 1

 

Test Temperature (ºC)

Test Volume (µL)

Ignition Delay (s)

Observations

200 (clean flask)

70

>300

No ignition, grey fumes emitted.

250 (clean flask)

70

25

Yellow flame, grey fumes emitted.

230

70

>300

No ignition, grey fumes emitted.

240

70

>300

No ignition, grey fumes emitted.

246

70

30

Yellow flame, grey fumes emitted.

244

70

>300

No ignition, grey fumes emitted.

244 (clean flask)

70

31

Yellow flame, grey fumes emitted.

242 (clean flask)

70

>300

No ignition, grey fumes emitted.

242 (clean flask)

200

76

Yellow flame, grey fumes emitted.

240 (clean flask)

200

>300

No ignition, grey fumes emitted.

240 (clean flask)

400

119

Yellow flame, grey fumes emitted.

238 (clean flask)

400

>300

No ignition, grey fumes emitted.

238 (clean flask)

600

140

Yellow flame, grey fumes emitted.

236 (clean flask)

600

>300

No ignition, grey fumes emitted.

236 (clean flask)

800

>300

No ignition, grey fumes emitted.

236 (clean flask)

1000

>300

No ignition, grey fumes emitted.

236 (clean flask)

1200

>300

No ignition, grey fumes emitted.

236 (clean flask)

1400

>300

No ignition, grey fumes emitted.

 

Room temperature:    20 °C
Atmospheric pressure: 98.1 to 98.8 kPa

Applicant's summary and conclusion

Conclusions:
The test item has been determined to have an auto-ignition temperature of 238 ± 5 °C.
Executive summary:

Test System The determination was carried out using a procedure designed to be compatible with Method A15 Auto-Ignition Temperature of Commission Regulation (EC) No 440/2008 of 30 May 2008.

Principle of the Test

The auto-ignition temperature is the lowest temperature at which the test item will ignite when mixed with air under the conditions defined in the test method.

Performance of the Test

The test flask was heated in a flask heater. Aliquots of test item (tested as received) were injected into the flask and the flask observed for signs of ignition over a 300 second period. This procedure was repeated, varying the sample size, as necessary, until the lowest temperature at which ignition, if any, occurred within 300 seconds of insertion, was determined.

The test item has been determined to have an auto-ignition temperature of 238 ± 5 °C.