Registration Dossier
Registration Dossier
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EC number: 213-969-1 | CAS number: 1070-10-6
Guidance on Safe Use
Administrative data
First-aid measures
4.1. Description of first aid measures
General advice
Take off all contaminated clothing immediately. Medical treatment is necessary if symptoms occur which are obviously caused by skin or eye contact with the product or by inhalation of its vapours.
Inhalation
Move subject to fresh air and keep him calm. In case of discomfort: Supply with medical care.
Skin contact
Wash off immediately with soap and water. If skin irritation occurs consult a physician.
Eye contact
Flush eyes thoroughly with a large amount of water and consult a physician.
Ingestion
Do not induce vomiting. Contact a doctor immediately.
4.2. Most important symptoms and effects, both acute and delayed
Skin irritation, Eye irritation
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
Fire-fighting measures
5.1. Extinguishing media
Suitable extinguishing media
foam, dry chemical, carbon dioxide
Extinguishing media which must not be used for safety reasons
water
5.2. Special hazards arising from the substance or mixture
May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.
5.3. Advice for firefighters
Wear self-contained breathing apparatus.
Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Assure sufficient ventilation. Use personal protective clothing. Keep away sources of ignition. Use breathing apparatus if exposed to vapours/dust/mist/aerosol. Do not eat, drink or smoke when using this product. Wash hands thoroughly with soap and water after handling.
6.2. Environmental precautions
Prevent product from getting into drains/surface water/groundwater.
6.3. Methods and material for containment and cleaning up
Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment! Smaller quantities and/or residues: Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust). Dispose of in accordance with regulations.
6.4. Reference to other sections
For personal protection see section 8.
Handling and storage
7.1. Precautions for safe handling
Safe handling advice
Keep container tightly closed. Ensure there is good room ventilation.
Advice on protection against fire and explosion
Take precautionary measures against static discharge. Keep away from sources of ignition In the event of fire, cool the endangered containers with water. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air. Use only explosion-proof equipment.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
Protect from the action of light. Keep away from heat. Keep away from sources of ignition - No smoking. Ensure there is good room ventilation. Store in a dry place. Protect against humidity and water. Keep only in the original container. Keep container tightly closed and store in a cool, well ventilated area.
7.3. Specific end use(s)
no
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 9003
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 9003
Shipping information
- Proper shipping name and description:
- UN 9003 SUBSTANCES WITH FLASHPOINT ABOVE 60°C, NOT EXCEEDING 100°C (contains Tetrakis(2-ethylhexyl)titanate), 9
- Chemical name:
- Tetrakis(2-ethylhexyl)titanate
- Language:
- English
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 9003
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 9003
Shippingopen allclose all
Special provisions / remarks
- Remarks:
- Not dangerous according to transport regulations.
Additional transport information
Additional information
- Special provisions / remarks / other:
- ADNR
Only if transported by inland tank barge: Dangerous goods class 9, Identification-No. 9003
Exposure controls / personal protection
8.1. Control parameters
see section 8.2.
8.2. Exposure controls
For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health
Protective measures
Do not breathe vapours. Avoid contact with eyes and skin. When using do not eat, drink or smoke.
Hygiene measures
Store work clothing separately. Take off all contaminated clothing immediately. Follow the usual good standards of occupational hygiene. Clean skin thoroughly after work; apply skin cream.
Respiratory protection
Breathing apparatus in case of high concentrations, short term: filter appliance, filter A
Hand protection
suitable protective gloves
In practice, due to variable exposure conditions, this information can only be an aid to orientation for the selection of a suitable chemical protection glove. In particular, this information does not substitute suitability tests by the end user.
General information
Gloves should be replaced regularly, especially after extended contact with the product. For each work-place a suitable glove type has to be selected.
Eye protection
tightly fitting goggles
Skin and body protection
Wear suitable protective clothing. On handling of larger quantities: face mask, chemical-resistant boots and apron
Stability and reactivity
10.1. Reactivity
see section 10.2.
10.2. Chemical stability
This material is considered stable under specified conditions of storage, shipment and/or use.No decomposition if used as directed.In contact with water or moisture:Hydrolysis
10.3. Possibility of hazardous reactions
None when used as directed.
10.4. Conditions to avoid
Avoid high temperatures and sources of ignition.Protect against humid air and water.
10.5. Incompatible materials
humid air and water (hydrolysis) Strong oxidizing agents Acids Bases
10.6. Hazardous decomposition products
None when used as directed. In contact with water or moisture:, Hydrolysis, Hydrolytic products, Titanium dioxide, TiO2, 2-ethylhexanol
Disposal considerations
13.1. Waste treatment methods
Product
Waste is hazardous. It must be disposed of in accordance with the regulations after consultation of the competent local authorities and the disposal company in a suitable and licensed facility.
Uncleaned packaging
Contaminated packages must be emptied as good as possible. They may then be recycled after proper cleaning. Packages that cannot be cleaned must be disposed of in the same way as the substance. Uncontaminated packaging may be taken for recycling.
Code of waste EWC
07 01 08
waste from the manufacture, formulation, supply and use (MFSU) of basic organic chemicals - other still bottoms and reaction residues
Always check the given waste codes according to the actual conditions of manufacturing, formulation or use in your facilities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
