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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Hazard for aquatic organisms

Freshwater

Hazard assessment conclusion:
PNEC aqua (freshwater)
PNEC value:
0.74 mg/L
Assessment factor:
10
PNEC freshwater (intermittent releases):
0.33 mg/L

Marine water

Hazard assessment conclusion:
PNEC aqua (marine water)
PNEC value:
0.043 mg/L

STP

Hazard assessment conclusion:
no hazard identified

Sediment (freshwater)

Hazard assessment conclusion:
no hazard identified

Sediment (marine water)

Hazard assessment conclusion:
no hazard identified

Hazard for air

Air

Hazard assessment conclusion:
no hazard identified

Hazard for terrestrial organisms

Soil

Hazard assessment conclusion:
PNEC soil
PNEC value:
43.6 mg/kg soil dw
Assessment factor:
10

Hazard for predators

Secondary poisoning

Hazard assessment conclusion:
no potential for bioaccumulation

Additional information

Conclusion on classification




In order to determine the classification for hazardous properties related to the aquatic environment, the criteria of the Regulation (EC) No 1272/2008 (CLP) version 2016 in Annex I were accurately followed.


Short-term (acute) aquatic hazard:


For classification, acute toxicity data are available for fish, aquatic invertebrates (Daphnia) and algae for the 3 different constituents of the reaction mass. 


The lowest LC50 or EC50 values observed for the different trophic levels in water are:


Fish: LC50 (96h) = 209.4 mg RM/L
Marine invertebrates: EC50 (96h) = 43.2 mg RM/L


Freshwater algae: EC50 (96h, growth rate) = 176 mg RM/L


The criteria in Table 4.1.0 (a) of Annex I of the CLP Regulation were applied.


The lowest LC50 or EC50 value was observed for marine invertebrates (Mysidopsis bahia) , which are hence the most sensitive species. According to Table 4.1.0 (a) the substance should not be classified for acute aquatic hazard, as the lowest EC50 value, EC50 (96h) for marine invertebrates = 43.2 mg RM/L, is larger than the cut-off for classification of 1 mg/L.


Please note that the test conditions for the short-term study on marine invertebrates, i.e. 96h, deviates from the default 48h for crustacea species. Nevertheless, it can reasonably be assumed that this longer testing period does not affect the conclusion to not classify the reaction mass for acute aquatic toxicity.


Long-term (chronic) aquatic hazard:





The information available on CaF2 have been used to derive the classification. 


Chronic data available for all 3 trophic levels: fish, aquatic invertebrates and algae. Since the biodegradability concept does not apply for inorganic substance, the approach as described for metals and metal compounds in ECHA guidance on the application of CLP criteria, has been used. The chronic ERV, or in this case NOEC values, used for classifcation are:


Fish (21d): NOEC >18.4 mg RM/L (lower values were reported in the Pearcy et al. 2015 study, with the lowest being 11.9 mg/L NaF, however, in a 7d chronic assessment). Therefore this value has not been selected as key value for C&L. Nevertheless, since also > 1 mg/L selecting it as key value would have no impact on the classification conclusion).


Daphnia (21d): NOEC = 15.2 mg RM/L


Algae (7d): NOEC = 205 mg RM/L


Since the lowest chronic ERVs or NOEC value, 15.2 mg RM/L is well above 1 mg/L, the reaction mass does not need to be classified for long term aquatic hazard.