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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Auto flammability

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
Name of test material (as cited in study report): 4-chlorobenzyl propargyl ether,
Analytical purity: 93,5 %
Lot/batch No.: LS 208804 Batch 10
Storage condition of test material: ambient temperature
Key result
Auto-ignition temperature:
377 °C
Atm. press.:
1 013.25 hPa

Results:

Test run no.

lowest temperature leading to auto ignition

[°C]

quantity of sample

[ml]

ignition delay time

[s]

1sttest series

383

0.05

8

2ndtest series

388

0.18

14

3rdtest series

391

0.10

14

The tests were performed at an atmospheric pressure of 1010 mbar – 1015 mbar.

From these test runs a corrected* auto-ignition-temperature of 377 °C results.

* Correction performed according to EN 14522.

Description of key information

The auto-ignition temperature of the test substance is 377 °C at 1013.25 hPa.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
377 °C

Additional information

A GLP study was conducted according to Regulation (EC) No 440/2008, Annex A.15.

The BASF GLP study no. SIK 16/0787 determined the auto-ignition temperature to be 377°C at 1013.25 hPa.