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Administrative data

Endpoint:
flash point of flammable liquids
Type of information:
experimental study
Adequacy of study:
key study
Study period:
25 July 2017 - 27 November 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2018
Report date:
2018

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.9 (Flash-Point)
Deviations:
no
Qualifier:
according to guideline
Guideline:
ASTM D93 (Standard test methods for flash point by pensky-martens closed cup tester)
Deviations:
no
Qualifier:
according to guideline
Guideline:
ISO 2719 (Determination of flash point - Pensky-Martens closed cup method)
Deviations:
no
Qualifier:
according to guideline
Guideline:
ISO 3679 (Determination of flash point - Rapid equilibrium closed cup method)
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: ASTM D7094: “Standard Test Method for Flash Point by Modified Continuously Closed Cup (MCCCFP) Tester”
Qualifier:
according to guideline
Guideline:
other: UN no. ST/SG/AC.10/11/Rev.6 “Non-Viscous Flammable Liquids”
Deviations:
no
Qualifier:
according to guideline
Guideline:
other: United Nations (UN), UN no. ST/SG/AC.10/11/Rev.6
Version / remarks:
United Nations (UN), UN no. ST/SG/AC.10/11/Rev.6: Recommendations on the Transport of
Dangerous Goods, Part III: Classification Procedures, Test Methods and Criteria Relating to
Class 2, Class 3, Class 4, Division 5.1, Class 8 and Class 9, Paragraph 32.4.1: “Non-Viscous
Flammable Liquids”, 2015.
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Type of method:
closed cup
Flash point apparatus:
other: Eraflash flash-point tester

Test material

Constituent 1
Chemical structure
Reference substance name:
Diethyl ethoxymethylenemalonate
EC Number:
201-725-7
EC Name:
Diethyl ethoxymethylenemalonate
Cas Number:
87-13-8
Molecular formula:
C10H16O5
IUPAC Name:
diethyl ethoxymethylenemalonate
Test material form:
liquid
Specific details on test material used for the study:
- Batch n°: JC170405
- Analytical purity: 99.5%
- Expiration date: 12 April 2018
- Storage condition: at room temperature

Results and discussion

Flash point
Key result
Flash point:
142 °C
Atm. press.:
1 013.25 hPa

Any other information on results incl. tables

Preliminary test

The estimated flash-point of the test item was 139°C.

Main study

The difference between the results obtained with the two tests was ≤ 6°C. From this, it was concluded that the flash-point of the test item is the lowest flash-point obtained.

 Test Flash-point

°C

 Lowest flash-point  

°C

 1 142  142 
 2 144  

Applicant's summary and conclusion

Interpretation of results:
GHS criteria not met
Conclusions:
The closed cup method was applied for the determination of the flash-point of JNJ-39005525-AAA (EMME).
The flash-point of the test item was 142°C.