1,2-Cyclohexanedicarboxylic Acid, 1-(phenylmethyl) ester, ester with 2,2,4-trimethyl, 1,3-petanediol mono(2-methyl propanoate)

Boiling point

Link to relevant study record(s)

Reference

Reference 1

Endpoint:

boiling point

Type of information:

experimental study

Adequacy of study:

key study

Reliability:

2 (reliable with restrictions)

Rationale for reliability incl. deficiencies:

other: according to ASTM D7169 but no description just results given

Qualifier:

according to guideline

Guideline:

other: ASTM D7169

GLP compliance:

not specified

Type of method:

other: according to ASTM D7169

Key result

Boiling pt.:

438.5 °C

Remarks on result:

other: 50% boiling point

Conclusions:

The 50% boiling point for Santicizer Platinum P1700 was 438.5 degrees C according to the National Standard Method ASTM D7169. No further description of the method is given in the report from Intertek, hence reliability score 2.

Executive summary:

The 50% boiling point for Santicizer Platinum P1700 was 438.5 degrees C according to the National Standard Method ASTM D7169. No further description of the method is given in the report from Intertek, hence reliability score 2.

Reference 2

Endpoint:

boiling point

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2015

Reliability:

2 (reliable with restrictions)

Rationale for reliability incl. deficiencies:

other: Internal email report of boiling point and vapour pressure assessment, guidelines not mentioned

Principles of method if other than guideline:

Notebook VSC1004-7
A 380.0 g of sample of P-1700 from Batch RP-1062 was placed in a 1-L flask and distilled under full vacuum of a mechanical pump (< 1mmHg, <240°C) until about 30 mL of liquid was condensed. The pressure was then adjusted and the material was distilled slowly under the corresponding pressure. The constant temperature was recorded as the boiling point under this pressure. There is no foaming (significant decomposition) at 312°C.

Conditions at 1 mm Hg were not ideal. A pressure of 1 mm Hg is beyond the accuracy of the vacuum gauge.

Data units were converted to utilize the gas constant R of 8.3144598 J K−1mol−1 in the The Clausius-Clapeyron equation, ln(𝑃)= −Δ𝐻𝑣𝑎𝑝𝑅(1𝑇)+𝐶. Hvap of 132,167 J/mol was found from the slope of the least squares fit of the ln[vp(Pa)] and 1/T(K) data. Using the Clausius-Clapeyron equation, the following have been extrapolated for P1700: vapor pressure at 25°C of 2.04 x 10-10 Torr and boiling point at 760 Torr of 379°C

GLP compliance:

not specified

Type of method:

distillation method

Key result

Boiling pt.:

247.7 °C

Atm. press.:

1 mm Hg

Decomposition:

no

Key result

Boiling pt.:

252.4 °C

Atm. press.:

2 mm Hg

Decomposition:

no

Key result

Boiling pt.:

257.9 °C

Atm. press.:

3 mm Hg

Decomposition:

no

Key result

Boiling pt.:

262.9 °C

Atm. press.:

4 mm Hg

Decomposition:

no

Key result

Boiling pt.:

267.5 °C

Atm. press.:

5 mm Hg

Decomposition:

no

Key result

Boiling pt.:

273.4 °C

Atm. press.:

7 mm Hg

Decomposition:

no

Key result

Boiling pt.:

281 °C

Atm. press.:

10 mm Hg

Decomposition:

no

Key result

Boiling pt.:

295.8 °C

Atm. press.:

20 mm Hg

Decomposition:

no

Key result

Boiling pt.:

304 °C

Atm. press.:

30 mm Hg

Decomposition:

no

Key result

Boiling pt.:

312 °C

Atm. press.:

50 mm Hg

Decomposition:

no

Key result

Boiling pt.:

379 °C

Atm. press.:

760 mm Hg

Remarks on result:

other: Extrapolated

Conclusions:

Vapor pressure of P1700 has been measured at reduced pressure. Using the Clausius-Clapeyron equation, the following have been extrapolated for P1700: vapor pressure at 25°C of 2.04 x 10-10 Torr, boiling point at 760 Torr of 379°C, and Heat of Vaporization of Hvap of 132,167 J/mol.

Executive summary:

Vapor pressure of P1700 has been measured at reduced pressure. Using the Clausius-Clapeyron equation, the following have been extrapolated for P1700: vapor pressure at 25°C of 2.04 x 10-10 Torr, boiling point at 760 Torr (1 atm) of 379°C, and Heat of Vaporization of Hvap of 132,167 J/mol.

Description of key information

Using the Clausius-Clapeyron equation, the following have been extrapolated for P1700: boiling point at 760 Torr of 379°C.

The 50% boiling point for Santicizer Platinum P1700 was 438.5°C according to the National Standard Method ASTM D7169.

Key value for chemical safety assessment

Boiling point at 101 325 Pa:

438.5 °C