1-[[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]methyl]-1H-1,2,4-triazole

Oxidising properties

Link to relevant study record(s)

Reference

Endpoint:

oxidising liquids

Type of information:

experimental study

Adequacy of study:

key study

Study period:

09 Mar 2000 to 10 Mar 2000

Reliability:

1 (reliable without restriction)

Rationale for reliability incl. deficiencies:

guideline study

Qualifier:

according to guideline

Guideline:

UN Manual of Tests and Criteria: Test O.3 (Gravimetric test for oxidizing solids)

Version / remarks:

Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria. Part III, section 34. United Nations, 1995

GLP compliance:

yes

Contact with:

powdered cellulose

Duration of test (contact time):

15.59 s

Key result

Sample tested:

test mixture 1:1

Parameter:

mean pressure rise time

Result:

15.59 s

Table 1. Test pressure rise time of a 1:1 mixture, Test Item and cellulose.

Test number:	Time (s) (1)	Mean time (s) for five trials
1	14,10	15,59
2	18,36
3	15, 02
5	14,28
7	16,20

(1) Time for the pressure to rise from 690 kPa to 2070 kPa, for the 1:1 Test Item and cellulose

mixture.

 

Table 2. The Test criteria for determining the oxidizing properties of the test item.

Mean time (s) for five trials (2)	Criteria	Mean time (s) for five trials (3)	Reference Item	Paking Group
-	LT	-	50% perchloric acid	I
-	GT or EQ	-	50% perchloric acid	II
-	and	-	and
-	LT	-	40% aqueous sodium chlorate solution
-	GT or EQ	-	40% aqueous sodium chlorate solution and	III
-	and	-	and
-	LT	-	65% aqueous nitric acid
15,59	GT or EQ	3,94	65% aqueous nitric acid	Not Division 5.1

(2) 1:1 Test Item and cellulose mixture

(3) 1:1 Reference Item and cellulose mixture

- LT: less than

- GT: greater than

- EQ: equal

Interpretation of results:

GHS criteria not met

Conclusions:

The test mixtures produced pressure rise from 690kPa to 2070kPa at 15.59s average for the 65% aqueous nitric acid/cellulose test item mixture and 3.94s average for the 65% aqueous nitric acid/cellulose reference item mixture. In accordance with the criteria of UN Manual of Tests and Criteria: Test O.3, the test substance is not classified as an oxidising substance.

Executive summary:

An oxidising properties study based on the UN Manual of Tests and Criteria: Test O.3 and in compliance with GLP has been conducted on the test substance. The test mixtures produced pressure rise from 690 kPa to 2070 kPa at 15.59s average for the 65% aqueous nitric acid/cellulose test item mixture and 3.94s average for the 65% aqueous nitric acid/cellulose reference item mixture. The test substance is not classified as an oxidising substance.

Description of key information

The test substance is not an oxidising substance, UN Manual of Tests and Criteria: Test O.3, Angly 2000.

Key value for chemical safety assessment

Oxidising properties:

non oxidising

Justification for classification or non-classification

Based on the available information, classification on oxidising properties is not warranted in accordance with EU Classification, Labelling and Packaging of Substances and Mixtures (CLP) Regulation No. (EC) 1272/2008.