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Physical & Chemical properties

Surface tension

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Reference
Endpoint:
surface tension
Type of information:
experimental study
Adequacy of study:
key study
Study period:
20 May 1992
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 115 (Surface Tension of Aqueous Solutions)
Qualifier:
according to guideline
Guideline:
other: ISO 304 (Surface active agents - Determination of Surface Tension by Drawing up Liquid Films)
GLP compliance:
yes
Type of method:
plate method
Key result
Surface tension:
70.1 mN/m
Temp.:
20 °C
Conc.:
10 g/L

RESULTS

DETERMINATION OF THE CORRECTION FACTOR

A correction factor Ob of 0.987 was found. No time dependence of surface tension was observed. The average surface of two independent measurements was 70.1 mN/m for a 10 g/L aqueous solution at 20.0 ± 0.2 °C.   

 

Table 1. Experiment 1: Surface tension by Wilhelmy plate method at 20.0 ± 0.2 °C

Concentration (g/L)

Minutes

σ (solution) / mN/m

σ correction for Ob (mN/m)

Filtrate of a 10.01 g/L suspension

0

70.4

 

 

1

70.2

 

 

5

69.8

 

 

10

69.3

 

 

15

69.0

 

 

20

68.7

 

 

25

68.4

 

 

30

68.1

 

Average

 

69.2

68.3

 

Table 2. Experiment 2: Surface tension by Wilhelmy plate method at 20.0 ± 0.2 °C

Concentration (g/L)

Minutes

σ (solution) / mN/m

σ correction for Ob (mN/m)

Filtrate of a 10.00 g/L suspension

0

73.8

 

 

 

1

73.8

 

 

5

73.8

 

 

10

73.7

 

 

15

73.7

 

 

20

73.7

 

Average

 

73.8

72.8

 

A Harkins - Jordan correction is required by the test guideline for measurements on aqueous solutions by the ring method. This hydrostatic correction is, however, not necessary when using the Wilhelmy plate method.

Conclusions:
The average surface tension of two independent measurements was 70.1 mN/m for a 10 g/L aqueous solution at 20.0 ± 0.2 °C.
Executive summary:

The surface tension of the test substance was determined using the Wilhelmy plate method in accordance with OECD TG 115 following GLP principles. The average surface tension of two independent measurements was 70.1 mN/m for a 10 g/L aqueous solution at 20.0 ± 0.2 °C.

Description of key information

Surface tension: 70.1 mN/m for 10 g/L aqueous solution at 20.0 ± 0.2 °C, OECD TG 115, Wilhelmy plate method, Ryser 1992

Key value for chemical safety assessment

Surface tension:
70.1
in mN/m at 20°C and concentration in mg/L:
10 000

Additional information