Registration Dossier
Registration Dossier
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EC number: 206-982-9 | CAS number: 407-25-0
Guidance on Safe Use
Administrative data
First-aid measures
If inhaled
- Move to fresh air.
- Oxygen or artificial respiration if needed.
- Victim to lie down in the recovery position, cover and keep him warm.
- Call a physician immediately.
In case of eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybuprocaine).
- Call a physician or poison control centre immediately.
- Take victim immediately to hospital.
In case of skin contact
- Take off contaminated clothing and shoes immediately.
- Wash off immediately with plenty of water.
- Keep warm and in a quiet place.
- Call a physician or poison control centre immediately.
- Wash contaminated clothing before re-use.
If swallowed
- Call a physician or poison control centre immediately.
- Take victim immediately to hospital.
- If swallowed, rinse mouth with water (only if the person is conscious).
- Do NOT induce vomiting.
- Artificial respiration and/or oxygen may be necessary.
Fire-fighting measures
Suitable extinguishing media
- Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Extinguishing media which shall not be used for safety reasons
- Never use water.
Special exposure hazards in a fire
- The product is not flammable.
- Reacts violently with water.
- Hazardous decomposition products formed under fire conditions.
- Gives off hydrogen by reaction with metals.
Special protective equipment for fire-fighters
- In the event of fire, wear self-contained breathing apparatus.
- Use personal protective equipment.
- Wear chemical resistant oversuit
Other information
- Cool containers / tanks with water spray.
- Keep from any possible contact with water.
Accidental release measures
Personal precautions
- Prevent further leakage or spillage if safe to do so.
- Keep away from Incompatible products.
Environmental precautions
- Do not flush into surface water or sanitary sewer system.
- If the product contaminates rivers and lakes or drains inform respective authorities.
Methods for cleaning up
- Dam up.
- Soak up with inert absorbent material.
- Prevent product from entering drains.
- Contact with water may produce heat release and presents risks of splashing.
- Keep in properly labelled containers.
- Keep in suitable, closed containers for disposal.
Handling and storage
Handling
- Clean and dry piping circuits and equipment before any operations.
- Used in closed system.
- Use only in well-ventilated areas.
- Keep away from incompatible products.
- To avoid thermal decomposition, do not overheat.
- Preferably transfer by pump or gravity.
Storage
- Store in original container.
- Store in a well-ventilated place. Keep cool.
- Keep in properly labelled containers.
- Keep container closed.
- Keep in a bunded area.
- Keep away from heat.
- Electrical equipment should be protected to the appropriate standard.
- Keep away from Incompatible products.
Packaging material
- Steel
- Polyethylene
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- ID Number: UN3265
Kemler Code: 88
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.(TRIFLUOROACETIC ANHYDRIDE)
- Chemical name:
- Trifluoroacetic anhydride
- Language:
- English
- Labels:
- 8 - Corrosive
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- ID Number: UN3265
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- ID Number: UN3265
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.(TRIFLUOROACETIC ANHYDRIDE)
- Chemical name:
- Trifluoroacetic anhydride
- Labels:
- 8 - Corrosive
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- ID Number: UN3265
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.(TRIFLUOROACETIC ANHYDRIDE)
- Chemical name:
- Trifluoroacetic anhydride
- Labels:
- 8 - Corrosive
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Exposure controls
- Provide appropriate exhaust ventilation at machinery.
Occupational exposure controls
Respiratory protection
- Use respirator when performing operations involving potential exposure to vapour of the product.
- Respirator with a vapour filter (EN 141)
- Recommended Filter type: B
- Self-contained breathing apparatus in case of: 1) large uncontrolled emissions, 2) insufficient oxygen, 3) the mask and cartridge do not give adequate protection.
Hand protection
- Impervious gloves
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
- Suitable material: Neoprene
Eye protection
- Chemical resistant goggles must be worn.
- If splashes are likely to occur, wear: Tightly fitting safety goggles, Face-shield
Skin and body protection
- Chemical resistant apron
- If splashes are likely to occur, wear: Apron, Boots, Neoprene
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- Take off contaminated clothing and shoes immediately.
- Wash contaminated clothing before re-use.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.
Stability and reactivity
Stability
- Stable under recommended storage conditions.
Possibility of hazardous reactions
- Reacts violently with water.
- Corrosive to many metals when in contact with water or humidity.
- Gives off hydrogen by reaction with metals.
- Keep away from strong bases.
- Risk of violent reaction.
- Risk of explosion.
Conditions to avoid
- To avoid thermal decomposition, do not overheat.
- Exposure to moisture.
- freezing
Materials to avoid
- Metals,
- Water,
- Strong bases,
- Alkalis,
- Oxidizing agents.
Hazardous decomposition products
- Hydrogen fluoride,
- Carbon monoxide,
- Trifluoroacetic acid.
Disposal considerations
Waste from residues / unused products
- In accordance with local and national regulations.
- Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities.
Packaging treatment
- To avoid treatments, as far as possible, use dedicated containers.
- Dispose of rinse water in accordance with local and national regulations.
- Clean container with water.
- The empty and clean containers are to be reused in conformity with regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
