Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

4.1. Description of first aid measures

First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). Immediately remove contaminated clothing.

If inhaled:

Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:

Immediately wash thoroughly with soap and water, seek medical attention.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open.

On ingestion:

Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11.

4.3. Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media:

dry powder, carbon dioxide, water spray

5.2. Special hazards arising from the substance or mixture

nitrogen oxides, carbon oxides

The substances/groups of substances mentioned can be released in case of fire.

5.3. Advice for fire-fighters

Special protective equipment:

Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:

Cool endangered containers with water-spray. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Avoid inhalation. Handle in accordance with good industrial hygiene and safety practice.

6.2. Environmental precautions

Do not empty into drains.

6.3. Methods and material for containment and cleaning up

For large amounts: Pump off product.

For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).

Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.

6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

7.1. Precautions for safe handling

Ensure thorough ventilation of stores and work areas. Product should be worked up in closed equipment as far as possible.

Protection against fire and explosion:

Vapours may form explosive mixture with air. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

7.2. Conditions for safe storage, including any incompatibilities

Segregate from foods and animal feeds. Segregate from oxidants.

Further information on storage conditions: Containers should be stored tightly sealed in a dry place. Avoid all sources of ignition: heat, sparks, open flame.

Storage stability:

Storage duration: 24 Months

From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

Transport information

Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

Shippingopen allclose all
Remarksopen allclose all
Shippingopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1. Control parameters

Components with occupational exposure limits

No occupational exposure limits known.

PNEC

freshwater: 0,5 mg/l

marine water: 0,05 mg/l

intermittent release: 5 mg/l

STP: 10000 mg/l

sediment (freshwater): 1,08 mg/kg

soil: 0,082 mg/kg

8.2. Exposure controls

Personal protective equipment

Respiratory protection:

Breathing protection if gases/vapours are formed. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)

Hand protection:

Chemical resistant protective gloves (EN 374)

Suitable materials also with prolonged, direct contact (Recommended:  Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):

chloroprene rubber (CR) - 0.5 mm coating thickness

butyl rubber (butyl) - 0.7 mm coating thickness

fluoroelastomer (FKM) - 0.7 mm coating thickness

Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:

Safety glasses with side-shields (frame goggles) (e.g. EN 166)

General safety and hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Females of childbearing age should not come into contact with the product. The substance was registered as a transported isolated intermediate. The manufacturer/importer has received the confirmation by the user that the substance is used under strictly controlled conditions in accordance with art. 18 of the REACH regulation (EC) No 1907/2006. Take off immediately all contaminated clothing. Store work clothing separately.

Stability and reactivity

10.1. Reactivity

Formation of flammable gases:       Remarks:       Forms no flammable gases in the presence of water.

10.2. Chemical stability

The product is chemically stable.

10.3. Possibility of hazardous reactions

No hazardous reactions if stored and handled as prescribed/indicated.

10.4. Conditions to avoid

See MSDS section 7 - Handling and storage.

10.5. Incompatible materials

Substances to avoid:

No substances known that should be avoided.

10.6. Hazardous decomposition products

Hazardous decomposition products:

nitrogen oxides

Disposal considerations

13.1. Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.

The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.

Contaminated packaging:

Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.

Categories Display