Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

1 Description of first aid measures
· General information:
No special measures required.
If symptoms persist consult doctor.
· After inhalation:
Supply fresh air.
· After skin contact:
Generally the product does not irritate the skin.
· After eye contact:
Rinse opened eye for several minutes under running water.
Remove contact lenses, if present and easy to do. Continue rinsing.
· After swallowing:
Rinse mouth.

2 Most important symptoms and effects, both acute and delayed
No further relevant information available.

3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

Fire-fighting measures

1 Extinguishing media
· Suitable extinguishing agents:
CO₂, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Use fire extinguishing methods suitable to surrounding conditions.
· For safety reasons unsuitable extinguishing agents:
Water with full jet

2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
In case of fire, the following can be released:
Carbon monoxide
Carbon dioxide
Nitrogen oxides (NOx)
Sulphur oxides (SOx)

3 Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
· Additional information:
Cool endangered receptacles with water spray.
Collect contaminated fire fighting water separately. It must not enter the sewage system.

Accidental release measures

1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation.
Wear protective clothing.
Avoid formation of dust.
Keep away from ignition sources.

2 Environmental precautions
Do not allow to enter sewers/ surface or ground water.

3 Methods and material for containment and cleaning up
Pick up mechanically.
Dispose of the material collected according to regulations.

Handling and storage

1 Precautions for safe handling
Prevent formation of dust.
Any unavoidable deposit of dust must be regularly removed.
Ensure good ventilation/exhaustion at the workplace.
· Information about fire and explosion protection:
Dust can combine with air to form an explosive mixture.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.

2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store only in the original receptacle.
· Information about storage in one common storage facility:
Store away from oxidising agents.
· Further information about storage conditions:
Store in cool, dry conditions in well sealed receptacles.
Store in the dark.

3 Specific end use(s)
No further relevant information available.

Transport information

Land transport (ADR/RID)

UN number:
UN3077
Proper shipping name and description:
3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (N-(1,1-dimethylethyl)bis(2-benzothiazolesulfen)amide)
Chemical name:
N-(1,1-dimethylethyl)bis(2-benzothiazolesulfen)amide)
Language:
English
Class:
9 Miscellaneous dangerous substances and articles
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN3077
Proper shipping name and description:
3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (N-(1,1-dimethylethyl)bis(2-benzothiazolesulfen)amide)
Chemical name:
N-(1,1-dimethylethyl)bis(2-benzothiazolesulfen)amide)
Language:
English
Class:
9 Miscellaneous dangerous substances and articles
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN3077
Proper shipping name and description:
3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (N-(1,1-dimethylethyl)bis(2-benzothiazolesulfen)amide), MARINE POLLUTANT
Chemical name:
N-(1,1-dimethylethyl)bis(2-benzothiazolesulfen)amide)
Class:
9 Miscellaneous dangerous substances and articles
Packaging group:
III
EmS code:
F-A,S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (N-(1,1-dimethylethyl)bis(2-benzothiazolesulfen)amide)
Chemical name:
N-(1,1-dimethylethyl)bis(2-benzothiazolesulfen)amide)
Class:
9 Miscellaneous dangerous substances and articles
Packaging group:
III
Labels:
9
Remarksopen allclose all

Additional transport information

Additional transport information
· Danger code (Kemler): 90
· Stowage Category: A
· Stowage Code: SW23 When transported in BK3 bulk container
· Tunnel restriction code (ADR/RID/ADN): E

Exposure controls / personal protection

1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.

2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Do not eat, drink, smoke or sniff while working.
Keep away from foodstuffs, beverages and feed.
The usual precautionary measures are to be adhered to when handling chemicals.
· Respiratory protection:
Not necessary if room is well-ventilated.
· Protection of hands:
Protective gloves and protective skin cream
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation.
· Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
Butyl rubber, BR
Nitrile rubber, NBR
PVC gloves
· Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Eye protection:
Safety glasses
· Body protection:
Protective work clothing

Stability and reactivity

1 Reactivity
No further relevant information available.

2 Chemical stability
No decomposition if used and stored according to specifications.
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.

3 Possibility of hazardous reactions
No dangerous reactions known.

4 Conditions to avoid
No further relevant information available.

5 Incompatible materials
No further relevant information available.

6 Hazardous decomposition products
No dangerous decomposition products known.

Disposal considerations

1 Waste treatment methods
· Recommendation:
Must be specially treated adhering to official regulations.

2 Uncleaned packaging
· Recommendation:
Disposal must be made according to official regulations.