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Diss Factsheets
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EC number: 210-248-3 | CAS number: 611-06-3
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Endpoint summary
Administrative data
Description of key information
The test substance is evaluated not to be irritating to the skin and not to tne mucous membranes of the eyes.
Key value for chemical safety assessment
Skin irritation / corrosion
Link to relevant study records
- Endpoint:
- skin irritation: in vivo
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: Guideline study and GLP.
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 404 (Acute Dermal Irritation / Corrosion)
- GLP compliance:
- yes
- Species:
- rabbit
- Strain:
- New Zealand White
- Type of coverage:
- semiocclusive
- Preparation of test site:
- shaved
- Vehicle:
- physiological saline
- Controls:
- not specified
- Amount / concentration applied:
- 500 mg/animal
- Duration of treatment / exposure:
- 4 h
- Observation period:
- 72 h
- Number of animals:
- 3
- Details on study design:
- With physiological saline moistened test substance was applied to the shaved skin and fixed with a plaster. After the 4 h exposure time the treatment area was rinsed with water observed for 72 hours and evaluated according to Draize
- Irritation parameter:
- overall irritation score
- Basis:
- mean
- Time point:
- other: 24, 48, 72 hours
- Score:
- 0
- Max. score:
- 4
- Reversibility:
- other: not irritating
- Remarks on result:
- other: not irritating
- Irritant / corrosive response data:
- the substance is evaluated to be non-irritating
- Other effects:
- -
- Executive summary:
In a skin irritation/corrosion study in rabbits according to OECD TG 404 and GLP the animals were treated with 500 mg of test substance moistened with 0.18 ml isotonic saline for 4 hours. 30 -60 minutes after patch removal in all animals a very slight erythem could be observed. After 24 hours after patch removal in all animals no irritation symptoms could be observed any more.
The test substance was evaluated to be not irritating according to directive 83/467/EWG.
Reference
Results:
Time after patch removal | 30 -60 min. | 24 h | 48 h | 72 h | ||||||||
Animal No: | 1 | 2 | 3 | 1 | 2 | 3 | 1 | 2 | 3 | 1 | 2 | 3 |
Formation of erythema and eschar | 1 | 1 | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
Formation of edema | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
Endpoint conclusion
- Endpoint conclusion:
- no adverse effect observed (not irritating)
Eye irritation
Link to relevant study records
- Endpoint:
- eye irritation: in vivo
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: guideline study but no GLP defined.
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 405 (Acute Eye Irritation / Corrosion)
- GLP compliance:
- not specified
- Species:
- rabbit
- Strain:
- New Zealand White
- Vehicle:
- unchanged (no vehicle)
- Controls:
- other: one eye of each rabbit served as control and remained untreated
- Amount / concentration applied:
- 100 mg
- Duration of treatment / exposure:
- 24 h
- Observation period (in vivo):
- 7 d
- Number of animals or in vitro replicates:
- 3
- Details on study design:
- 24 hours affter application of test item into the conjunctival sac, the treated eye was rinsed with saline.
- Irritation parameter:
- other: according to DRAIZE
- Basis:
- mean
- Time point:
- other: 24, 48 and 72 h
- Score:
- 0
- Max. score:
- 110
- Reversibility:
- fully reversible
- Remarks on result:
- other: not irritating
- Other effects:
- -
- Interpretation of results:
- not irritating
- Remarks:
- Migrated information
- Executive summary:
In an eye irritation study according to OECD 405 3 rabbits were treated with 0.1 g of the test substance. One eye of each test animal remained untreated and served as control. After 24 h the treated eye was flushed with with saline. The observation period was 7 d. According to DRAIZE the substance was found to be not irritating.
Reference
Reading | 1 h | 24 h | 48 h | 72 | ||||||||||||
Animal No. | 19 | 20 | 21 | 19 | 20 | 21 | 19 | 20 | 21 | 19 | 20 | 21 | ||||
1. Cornea | ||||||||||||||||
a) cloudiness | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||||
b) surface | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||||
a=A*B*5 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||||
2. Iris | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||||
b=A*5 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||||
3.conjunctiva | ||||||||||||||||
a) reddening | 1 | 1 | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||||
b) swelling | 1 | 1 | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||||
c) defluxion | 1 | 1 | 1 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||||
c=(A+B+C)*2 | 6 | 6 | 6 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | ||||
Total= a+b+c | 6 | 6 | 6 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 |
Primary irritation value: 0/9= 0.0
Endpoint conclusion
- Endpoint conclusion:
- no adverse effect observed (not irritating)
Additional information
SKIN IRRITATION
In a skin irritation/corrosion study in rabbits according to OECD TG 404 and GLP the animals were treated with 500 mg of test substance moistened with 0.18 ml isotonic saline for 4 hours. 30 -60 minutes after patch removal in all animals a very slight erythema could be observed. 24 hours after patch removal in all animals no irritation symptoms could be observed any more. Based on these observations the test substance was evaluated to be not irritating according to directive 83/467/EWG (Hofmann/Weigand 1986). Thus, the study of Hofmann/Weigand (1986) confirme the evaluation of a former skin irritation/corrosion study which was also performed according to OECD 404 (Suberg 1982) in which 3 rabbits were treated with 0.5 g of test substance fixed to the right flank of each animal for 4 h. The observation period was 7d. The untreated flank served as control. Very slight erythema and in one animal a slight and reversible edema was observed. These very slight irritational effects do not lead to classification and therefore the test substance was evaluated to be not irritating.
EYE IRRITATION
In an eye irritation study according to OECD 405 3 rabbits were treated with 0.1 g of the test substance. One eye of each test animal remained untreated and served as control. After 24 h the treated eye was flushed with saline. The observation period was 7 d. According to DRAIZE the substance was found to be not irritating (Suberg H., Bayer AG, 1982). An additional eye irritation study which was also performed according to OECD guideline 405 and GLP (Hofmann/Weigand 1986), confirmed this result.
Justification for selection of skin irritation / corrosion endpoint:
The study was performed according to guideline and GLP and evaluated with Klimisch score 1
Justification for selection of eye irritation endpoint:
a carefully reported guideline study but no GLP mentioned
Justification for classification or non-classification
Based on the available data no classification/labelling is required.
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