Registration Dossier
Registration Dossier
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EC number: 941-718-2 | CAS number: -
Auto flammability
Administrative data
Link to relevant study record(s)
- Endpoint:
- auto-ignition temperature (liquids)
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- Experimental Starting Date: 03 December 2013 Experimental Completion Date: 10 March 2014
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Remarks:
- Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of the relevant results. The study report was conclusive, done to a valid guideline and the study was conducted under GLP conditions.
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
- Deviations:
- no
- GLP compliance:
- yes
- Auto-ignition temperature:
- 216 °C
- Atm. press.:
- 102.2 - 102.5 kPa
- Conclusions:
- An auto-ignition temperature value of 216 ± 5 °C at 102.2 - 102.5 kPa was determined for the substance using a relevant test method. The result is considered reliable.
- Executive summary:
The determination was carried out using a procedure[1]designed to be compatible with Method A15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.
[1] Based on, Anon (1987), Electrical Apparatus for Explosive Gas Atmospheres. Part 4: Method of Test for Ignition Temperature. IEC Publications79-4, P1-19.
Conclusion The test item has been determined to have an auto-ignition temperature of 216 ± 5 °C.
- Endpoint:
- auto-ignition temperature (liquids)
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- Experimental Starting Date: 03 December 2013 Experimental Completion Date: 10 March 2014
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Remarks:
- Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of the relevant results. The study report was conclusive, done to a valid guideline and the study was conducted under GLP conditions.
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
- Deviations:
- no
- GLP compliance:
- yes
- Auto-ignition temperature:
- 212 °C
- Atm. press.:
- 100.8 - 102.6 kPa
- Remarks on result:
- other: The test item has been determined to have an auto-ignition temperature of 212 ± 5 °C.
- Conclusions:
- An auto-ignition temperature of 212 ± 5°C at 100.8 - 102.6 kPa was determined for the substance using a relevant test method. The result is considered reliable.
- Executive summary:
The determination was carried out using a procedure* designed to be compatible with Method A15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.
*Based on, Anon (1987), Electrical Apparatus for Explosive Gas Atmospheres. Part 4: Method of Test for Ignition Temperature. IEC Publications79-4, P1-19.
Conclusion
The test item has been determined to have an auto-ignition temperature of 212 ± 5 °C.
- Endpoint:
- auto-ignition temperature (liquids)
- Type of information:
- read-across from supporting substance (structural analogue or surrogate)
- Adequacy of study:
- weight of evidence
- Justification for type of information:
- 1. Hypothesis for the analogue approach:
The hypothesis for the analogue approach is that both the registration substance, Hydrocarbons, C9-C11, n-alkanes, isoalkanes, <2% aromatics (target substance), and the test substances, Hydrocarbons, C8-C11, n-alkanes, isoalkanes, <2% aromatics (source substance) and Hydrocarbons, C9-C12, n-alkanes, isoalkanes, <2% aromatics (source substance), are produced from the same Fischer-Tropsch substance, GTL Gasoil, by fractional distillation. The substances are members of the C9-C14 Aliphatics [≤2% Aromatics] Hydrocarbon Solvents Category.
The source substances contain the all of the constituents of the target substance. The substances have constituents that are part of the same homologous series and have many constituents in common. The substances therefore have qualitatively similar properties (RAAF Scenario 2 applies).
2. Source and target chemical(s)
The source substance Hydrocarbons, C8-C11, n-alkanes, isoalkanes, <2% aromatics is composed of linear, branched and cyclic hydrocarbons of chain length C8-C11
The source substance Hydrocarbons, C9-C12, n-alkanes, isoalkanes, <2% aromatics, is composed of linear, branched and cyclic hydrocarbons of chain length C9-C12
The target substance, Hydrocarbons, C9-C11, n-alkanes, isoalkanes, <2% aromatics, is composed of linear, branched and cyclic hydrocarbons of chain length C9-C11.
3. Analogue approach justification
The constituents of the source and target substances are all hydrocarbons. Identical constituents have identical physicochemical profiles. The source substances cover the full carbon chain length of the target substance. - Reason / purpose for cross-reference:
- read-across source
- Reason / purpose for cross-reference:
- read-across source
- Auto-ignition temperature:
- 216 °C
- Atm. press.:
- 102.2 - 102.5 kPa
- Auto-ignition temperature:
- 212 °C
- Atm. press.:
- 100.8 - 102.6 kPa
- Remarks on result:
- other: The test item has been determined to have an auto-ignition temperature of 212 ± 5 °C.
- Auto-ignition temperature:
- 270 °C
- Atm. press.:
- 1 atm
- Auto-ignition temperature:
- > 200 °C
- Atm. press.:
- 1 atm
Referenceopen allclose all
Results
Results of the auto-ignition temperature determination are shown in the following table.
Table 1: Auto-ignition results
Test Temperature (ºC) |
Test Volume (µL) |
Ignition Delay (s) |
Observations |
200 (clean flask) |
70 |
> 300 |
No ignition. |
250 (clean flask) |
70 |
15 |
Yellow flame, grey fumes emitted. |
230 |
70 |
> 300 |
No ignition, grey fumes emitted. |
240 (clean flask) |
70 |
> 300 |
No ignition, grey fumes emitted. |
246 |
70 |
> 300 |
No ignition, grey fumes emitted. |
248 (clean flask) |
70 |
> 300 |
No ignition, grey fumes emitted. |
248 (clean flask) |
200 |
13 |
Yellow flame, grey fumes emitted. |
246 (clean flask) |
200 |
13 |
Yellow flame, grey fumes emitted. |
242 |
200 |
19 |
Yellow flame, grey fumes emitted. |
238 |
200 |
22 |
Yellow flame, grey fumes emitted. |
234 |
200 |
32 |
Yellow flame, grey fumes emitted. |
230 |
200 |
37 |
Pale blue/yellow flame, grey fumes emitted. |
226 |
200 |
> 300 |
No ignition, grey fumes emitted. |
228 (clean flask) |
200 |
46 |
Pale blue/yellow flame, grey fumes emitted. |
226 (clean flask) |
200 |
59 |
Yellow flame, grey fumes emitted. |
224 (clean flask) |
200 |
48 |
Yellow flame, grey fumes emitted. |
220 (clean flask) |
200 |
> 300 |
No ignition, grey fumes emitted. |
222 (clean flask) |
200 |
> 300 |
No ignition, grey fumes emitted. |
222 (clean flask) |
400 |
> 300 |
No ignition, grey fumes emitted. |
222 (clean flask) |
600 |
69 |
Pale blue flame, grey fumes emitted. |
220 (clean flask) |
600 |
154 |
Pale blue flame, grey fumes emitted. |
218 (clean flask) |
600 |
> 300 |
No ignition, grey fumes emitted. |
218 (clean flask) |
800 |
162 |
Pale blue flame, grey fumes emitted. |
216 (clean flask) |
800 |
165 |
Pale blue flame, grey fumes emitted. |
214 (clean flask) |
800 |
> 300 |
No ignition, grey fumes emitted. |
214 (clean flask) |
1000 |
> 300 |
No ignition, grey fumes emitted. |
214 (clean flask) |
1200 |
> 300 |
No ignition, grey fumes emitted. |
214 (clean flask) |
1400 |
> 300 |
No ignition, grey fumes emitted. |
214 (clean flask) |
1600 |
> 300 |
No ignition, grey fumes emitted. |
Room temperature: 20 to 21 °C
Atmospheric pressure:102.2 to 102.5 kPa
Results
Results of the auto-ignition temperature determination are shown in the following table.
Table 1: Auto-ignition temperature results
Test Temperature (ºC) |
Test Volume (µL) |
Ignition Delay (s) |
Observations |
200 (clean flask) |
70 |
> 300 |
No ignition. |
250 (clean flask) |
70 |
10 |
Yellow flame, grey fumes emitted. |
240 |
70 |
> 300 |
No ignition, grey fumes emitted. |
246 |
70 |
13 |
Yellow flame, grey fumes emitted. |
242 |
70 |
> 300 |
No ignition, grey fumes emitted. |
244 (clean flask) |
70 |
14 |
Yellow flame, grey fumes emitted. |
242 (clean flask) |
70 |
> 300 |
No ignition, grey fumes emitted. |
242 (clean flask) |
200 |
16 |
Yellow flame, grey fumes emitted. |
240 (clean flask) |
200 |
19 |
Yellow flame, grey fumes emitted. |
238 (clean flask) |
200 |
24 |
Yellow flame, grey fumes emitted. |
236 (clean flask) |
200 |
24 |
Yellow flame, grey fumes emitted. |
234 (clean flask) |
200 |
27 |
Yellow flame, grey fumes emitted. |
232 (clean flask) |
200 |
26 |
Yellow flame, grey fumes emitted. |
230 (clean flask) |
200 |
33 |
Yellow flame, grey fumes emitted. |
228 (clean flask) |
200 |
36 |
Yellow flame, grey fumes emitted. |
224 |
200 |
54 |
Yellow flame, grey fumes emitted. |
220 |
200 |
> 300 |
No ignition, grey fumes emitted. |
222 (clean flask) |
200 |
69 |
Yellow flame, grey fumes emitted. |
220 (clean flask) |
200 |
62 |
Yellow flame, grey fumes emitted. |
218 (clean flask) |
200 |
144 |
Yellow flame, grey fumes emitted. |
216 (clean flask) |
200 |
> 300 |
No ignition, grey fumes emitted. |
216 (clean flask) |
400 |
83 |
Yellow/blue flame, grey fumes emitted. |
214 (clean flask) |
400 |
> 300 |
No ignition, grey fumes emitted. |
214 (clean flask) |
600 |
203 |
Pale blue flame, grey fumes emitted. |
212 (clean flask) |
600 |
79 |
Pale blue flame, grey fumes emitted. |
210 (clean flask) |
600 |
> 300 |
No ignition, grey fumes emitted. |
210 (clean flask) |
800 |
> 300 |
No ignition, grey fumes emitted. |
Table 2 (continued)
Test Temperature (ºC) |
Test Volume (µL) |
Ignition Delay (s) |
Observations |
210 (clean flask) |
1000 |
> 300 |
No ignition, grey fumes emitted. |
210 (clean flask) |
1200 |
> 300 |
No ignition, grey fumes emitted. |
210 (clean flask) |
1400 |
> 300 |
No ignition, grey fumes emitted. |
Room temperature: 20°C
Atmospheric pressure: 100.8 to 102.6 kPa
Description of key information
Auto-flammability: 212-216°C (measured)
Key value for chemical safety assessment
Additional information
There are no reliable measured auto-ignition data for the submission substance. However, reliable data are available for related substances in the relevant carbon number range, including other Fischer-Tropsch process-derived substances.
In EU Method A.15 studies, which were conducted in compliance with GLP, Hydrocarbons, C8-C11, n-alkanes, isoalkanes, <2% aromatics (GTL Solvent GS160) and Hydrocarbons, C9-C12, n-alkanes, isoalkanes, <2% aromatics (GS170) had measured auto-ignition temperature values of 216 ± 5°C at 102.2 -102.5 kPa and 212 ± 5°C at 100.8 - 102.6 kPa respectively. The results are considered to be reliable and are used as weight of evidence.
Hydrocarbons, C9-C11, n-alkanes, isoalkanes, cyclics, <2% aromatics has an auto-ignition temperature of >200°C at 1013 hPa using relevant test method.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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