Registration Dossier

Diss Factsheets

Administrative data

Hazard for aquatic organisms

Freshwater

Hazard assessment conclusion:
PNEC aqua (freshwater)
PNEC value:
0.03 mg/L
Assessment factor:
1 000
Extrapolation method:
assessment factor
PNEC freshwater (intermittent releases):
0.3 mg/L

Marine water

Hazard assessment conclusion:
PNEC aqua (marine water)
PNEC value:
0.003 mg/L
Assessment factor:
10 000
Extrapolation method:
assessment factor

STP

Hazard assessment conclusion:
PNEC STP
PNEC value:
0.4 mg/L
Assessment factor:
10
Extrapolation method:
assessment factor

Sediment (freshwater)

Hazard assessment conclusion:
PNEC sediment (freshwater)
PNEC value:
0.172 mg/kg sediment dw
Extrapolation method:
equilibrium partitioning method

Sediment (marine water)

Hazard assessment conclusion:
PNEC sediment (marine water)
PNEC value:
0.017 mg/kg sediment dw
Extrapolation method:
equilibrium partitioning method

Hazard for air

Air

Hazard assessment conclusion:
no hazard identified

Hazard for terrestrial organisms

Soil

Hazard assessment conclusion:
PNEC soil
PNEC value:
0.017 mg/kg soil dw
Extrapolation method:
equilibrium partitioning method

Hazard for predators

Secondary poisoning

Hazard assessment conclusion:
no potential for bioaccumulation

Additional information

PTSI is extremely water-reactive. It will react immediately with moisture to form p-toluenesulfonyl amide (PTSA) and carbon dioxide. Therefore the chemical safety assessment is conducted for the decomposition product PTSA.

Conclusion on classification

PTSI is extremely water-reactive. It will react immediately with moisture to form p-toluenesulfonyl amide (PTSA) and carbon dioxide. For the decomposition product PTSA, three acute aquatic toxicity tests are available. The lowest E(L)C50 in these tests was a 72h-EC50 of 30 mg/l for algae. This could lead to classification according to the DSD (Directive 67/548/EEC) and CLP (Regulation 1272/2008/EC), but only in combination with a long-term hazard.

PTSA is readily biodegradable and has a log Kow of 0.6. Therefore classification for long-term hazards to the environment is not required.

Based on the above, PTSI and PTSA are not classified for environmental hazards according to the DSD (Directive 67/548/EEC) and CLP (Regulation 1272/2008/EC).