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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Auto flammability

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Administrative data

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Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2009-09-23
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Test procedure in accordance with national standard methods (ASTM) witout GLP.
Qualifier:
according to guideline
Guideline:
other: ASTM E 659
Deviations:
no
GLP compliance:
no
Auto-ignition temperature:
ca. 313 °C
Atm. press.:
ca. 1 atm
Remarks on result:
other:
Relative self-ignition temperature:
ca. 313 °C
Remarks on result:
other:
Remarks:
at atm. press. of ca.1.0 atm

Measurement

Autoignition Temperature: 313°C

Conclusions:
The autoignition temperature was found to be 313 °C.
Executive summary:

Hexan-1-ol was determined according ASTM E 659. The selfignition point was determined to be 313 °C at atmospheric pressure.

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
supporting study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: This result was obtained from a reference source of chemical safety data which is peer-reviewed
Principles of method if other than guideline:
No details are available on the guideline used to determine this result.
GLP compliance:
not specified
Auto-ignition temperature:
290 °C
Atm. press.:
other: Please refer to Remarks
Remarks on result:
other:
Relative self-ignition temperature:
290 °C
Remarks on result:
other:
Remarks:
at atm. press. of other:Please refer to Remarks

The atmospheric pressure at which this result was determined is not stated.

Conclusions:
An auto-ignition value of 290ºC is reported in a collection of reliable data which has been subject to peer-review . The result is considered to be reliable.

Description of key information

The auto-ignition temperature of hexan-1-ol is 313°C at 1013 hPa.

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
313 °C

Additional information

The auto-ignition temperature of 313°C at 1013 hPa was determined in accordance with ASTM E 659. The result is considered to be reliable.

It is supported by a value of 290°C, taken from a source of hazard reference data (the online International Chemical Safety Cards of WHO IPCS).

Discussion of trends in the Category of C6-24 linear and essentially-linear aliphatic alcohols:

As carbon number increases, auto-ignition temperature generally decreases. Molecular weight is higher and intermolecular forces in the substance are all higher.