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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

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Reference
Endpoint:
relative self-ignition temperature (solids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
28 Nov 2014
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
guideline study with acceptable restrictions
Reason / purpose for cross-reference:
reference to same study
Qualifier:
according to guideline
Guideline:
other: VDI 2263 (Grewer oven test)
Deviations:
yes
Remarks:
Grewer oven test was performed as a preliminary test to the UN Test N.4, which was not done. Atmospheric pressure was not reported.
GLP compliance:
yes
Remarks:
The Department of Health of the Government of the United Kingdom
Remarks on result:
no self ignition observed under the test conditions
Remarks:
at atm. press. of ca.1013.0 hPa

Atmospheric pressure was not reported (assumed to be ca. 1013 hPa).

On completion of testing a crusty black/brown material remained.

Exothermic activity observed during the test: yes

Time when sample temperature exceeded reference temperature: 140.5 min

Oven temperature when sample temperature exceeded reference temperature: 307 °C

The substance could be excluded from classification as a self-heating solid of UN Class 4.2 as the onset temperature in the screening test exceeded 220 °C. The UN N.4 test was not performed.

Description of key information

no self-ignition
onset temperature 307 °C at ca. 1013 hPa (VDI 2263, preliminary to UN N.4)

Key value for chemical safety assessment

Additional information

The reported temperature is the Grewer oven temperature when sample temperature exceeded reference temperature. The substance could be excluded from classification as a self-heating solid of UN Class 4.2 as the onset temperature in the screening test exceeded 220 °C.