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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flammability

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Description of key information

Phosphine is highly flammable and spontaneously flammable in air. The lower and upper

explosion limit are, respectively, 1.8% and 98%.

Key value for chemical safety assessment

Flammability:
highly flammable

Additional information

Phosphine is highly flammable and spontaneously flammable in air. The lower and upper explosion limit are, respectively, 1.8% and 98%.


Flammability additional key value for CSA: spontaneously flammable in air (pyrophoric)

Justification for classification or non-classification

Phosphine is listed on Annex VI to Regulation (EC) No 1272/2008 includes lists of harmonised classification and labelling.

On table 3.2 (classification and labelling in accordance with the criteria set up in Annex VI to Directive 67/548/EEC), phosphine is listed with extremely flammable R12 and spontaneously flammable in air R17 (F+, extremely inflammable). No change to this classification is proposed.

On table 3.1 (classification and labelling in accordance with the criteria set up in Annex I to Regulation 1272/2008/EEC), phosphine is listed with extremely flammable gas H220 (Flam. Gas. Category 1). No change to this classification is proposed.