Registration Dossier
Registration Dossier
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EC number: 206-019-2 | CAS number: 288-32-4
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
First aid personnel should pay attention to their own safety. If the patient is likely to become
unconscious, place and transport in stable sideways position (recovery position). Immediately remove
contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately inhale corticosteroid dose
aerosol.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam
Special hazards arising from the substance or mixture
carbon oxides, nitrogen oxides
The substances/groups of substances mentioned can be released in case of fire.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent
systems.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use breathing apparatus if exposed to vapours/dust/aerosol. Avoid contact with the skin, eyes and
clothing.
Environmental precautions
Discharge into the environment must be avoided.
Methods and material for containment and cleaning up
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Pick up with suitable appliance and dispose of.
Handling and storage
Precautions for safe handling
Breathing must be protected when large quantities are decanted without local exhaust ventilation.
Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should
be kept handy. Avoid dust formation. Dust can form an explosive mixture with air.
Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances.
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Storage stability:
Storage duration: 18 Months
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Components with workplace control parameters
No occupational exposure limits known.
PNEC
freshwater: 0.13 mg/l
PNEC
marine water: 0.013 mg/l
intermittent release: 1.3 mg/l
sediment (freshwater): 0.336 mg/kg
sediment (marine water): 0.0336 mg/kg
soil: 0.0425 mg/kg
STP: 10 mg/l
DNEL
worker:
Long-term exposure- systemic effects, Inhalation: 10.6 mg/m3
worker:
Long-term exposure- systemic effects, dermal: 1.5 mg/kg
Exposure controls
Personal protective equipment
Respiratory protection:
Breathing protection if breathable aerosols/dust are formed. Particle filter with high efficiency for solid
and liquid particles (e.g. EN 143 or 149, Type P3 or FFP3).
Consider the risk management measures as outlined in the exposure scenario.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
fluoroelastomer (FKM) - 0.7 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
polyvinylchloride (PVC) - 0.7 mm coating thickness
butyl rubber (butyl) - 0.7 mm coating thickness
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2,
corresponding > 30 minutes of permeation time according to EN 374)
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in practice
may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of
dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin,
eyes and clothing. Do not breathe dust. Females of childbearing age should not come into contact with
the product.
Stability and reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
Reacts with strong acids. Exothermic reaction. Dust explosion hazard.
Conditions to avoid
See section Handling and storage.
Incompatible materials
Substances to avoid:
strong acids
Hazardous decomposition products
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to
dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in
cooperation with disposal agency/manufacturer/authorities.
Contaminated packaging:
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
Uncontaminated packaging can be re-used.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
