Registration Dossier

Administrative data

First-aid measures

4.1 Eye contact:
- Consult a doctor/medical service if irritation persists
- Rinse immediately with plenty of water
- Do not apply neutralizing agentss
4.2 Skin contact:
- Consult a doctor/medical service if irritation persists
- Soap may be used
- Wash immediately with lots of water
- Remove closing before washing
4.3 After inhalation:
- Immediately consult a doctor/medical service
- Remove the victim into fresh air
- Unconscious: maintain adequate airway and respiration
4.4 After ingestion:
- Immediately consult a doctor/medical service
- Never give water to an unconscious person
- Victim is fully conscious: immediately induce vomiting
- give nothing or little to drink

Fire-fighting measures

5.1 Suitable extinguishing media:
- Water spray
- Polyvalent foam
- ABC powder
- Carbon dioxide
5.2 Unsuitable extinguishing media:
- No data available
5.3 Special exposure hazards*
- Combustible
- Its dust is explosive with air
- On burning: release of toxic and corrosive gases/vapours (nitrous vapours, carbon monooxide - carbon dioxide)
5.4 Instructions:
- Dilute toxic gases with water spray
- Take account of toxic firefighting water
- Use firefighting water moderately and contain it
5.5 Special protective equipment for firefighters:
- Heat/fire exposure: compressed air/oxigen apparatus
- Dust cloud production: compressed air/oxygen apparatus

Accidental release measures

6.1 Personal protection/precautions:
See heading 8.2/8.3/13
6.2 Environmental precautions:
- Prevent soil and water pollution
- Prevent spreading in sewers
- Contain released substance, pump over in suitable containers
- Plug the leak, cut off the suply
- Dam up the solid spill
- Knock down/dilute dust cloud with water spray
6.3 Methods for cleaning up:
- Stop dust cloud by covering with sand/earth
- Carefully collect the spill/leftovers
- Scope solid spill into closing containers
- Powderd: do not use compressed air for pumping over spills
- Clean contaminated surfaces with an excess of water
- Take collected spill to manufacturer/competent authority
- Wash clothing and equipment after handling

Handling and storage

7.1 Handling:
- Observe very strict hygiene - avoide contact
- Avoid raising dust
- Take precautions against electrostatic charges
- Do not discharge the waste into the drain
- Remove contaminated clothing immediately
7.2 Storage
- Keep container tightly closed
- Store in a dry area
- Store in a dark area
- Meet the legal requirements
- keep away from: heat sources, ignition sources, oxidizing agents, water
Storage temperature: < 40 degreeC
Quantity limits: Not determined
Storage life: Not determined
Materials for packaging:
- suitable: paper
- to avoide: no data available
7.3 Specific uses:
- See information supplied by the manufacturer

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
2811
Shipping information
Proper shipping name and description:
Toxic solid, organic, n.o.s.
Chemical name:
N-phenylmaleimide
Language:
English
Labels:
a diamond- shaped figure with 'UN 2811'
Special provisions / remarks
Special provisions:
'LQ'
Remarks:
in the case of different goods with different identification numbers within a single package

Inland waterway transport (UN RTDG/ADN(R))

UN number:
2811
Shipping information
Proper shipping name and description:
Toxic solid, organic, n.o.s.
Chemical name:
N-phenylmaleimide
Language:
English
Labels:
a diamond- shaped figure with 'UN 2811'
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
2811
Shipping information
Proper shipping name and description:
Toxic solid, organic, n.o.s.
Chemical name:
N-phenylmaleimide
Labels:
a diamond- shaped figure with 'UN 2811'
Marine pollutant
Special provisions / remarks
Remarks:
96h-LC50 <1 mg/L, >0.1 mg/L

Air transport (UN RTDG/ICAO/IATA)

UN number:
2811
Shipping information
Proper shipping name and description:
Toxic solid, organic, n.o.s.
Chemical name:
N-phenylmaleimide
Labels:
a diamond- shaped figure with 'UN 2811'
Remarksopen allclose all

Additional transport information

Additional information
Special provisions / remarks / other:
none

Exposure controls / personal protection

8.1 Exposure limit value
- Other route: <0.1 mg/m3 (Japanese ABS resin manufacturers association)
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Work under local exhaust/ventilation
8.2.2 Environmental exposure controls:
See heading 13
8.3 Personal protection:
- Air line hood or mask, gloves, full chemical suit, boots are recommended
8.3.1 respitarory protection:
- Dust production: dust mask with filter type P3
8.3.2 hand protection:
- Gloves
suitable materials: Rubber
- Breakthrough time: Not determined
8.3.3 eye protection:
- Face shield
- In case of dust production: protective goggles
8.3.4 skin protection:
- Protective clothing
- Incase of dust production: head/neck protection
Suitable materials: Rubber

Stability and reactivity

10.1 Conditios to avoid/reactivity:
- Unstable on exposure to moisture
- Discolours on exposure to light
10.2 Materials to avoide:
- Keep away from: heat sources, ignition sources, oxidizing agents, water
10.3 Hazardous decomposition products:
- Hydrolyzes on exposure to water (moisture)
- On burning: release of toxic and corrosive gases/vapours (nitrous vapours, carbon monooxide - carbon dioxide)

Disposal considerations

13.1 Provisions relating to waste:
- Waste material code (Flanders) : 001
- Hazardous waste (91/689/EEC)
13.2 Disposal methods:
- Remove to an authorized incinerator equipped with an afterburner and a flue gas scrubber
- Do not dischrge into drains or the environment
13.3 Packaging/Container:
- Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of 16/2/2001): 15 01 10* (packaging residues of or contaminated by dangerous substances)