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Diss Factsheets

Physical & Chemical properties

Auto flammability

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Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
07 December 2015 - 26 July 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
Identity: RM1006114
Appearance: White creamy solid (at 20°C)
Storage conditions: Room temperature (15 to 25°C)
Batch number: RL 686/15
Purity: 100%
Expiry date: 30 October 2018
Date received: 12 November 2015
Key result
Auto-ignition temperature:
ca. 370 °C
Atm. press.:
>= 1 012 - <= 1 022 mBar
Conclusions:
The substance was evaluated for auto flammability in accordance with EU Method A.15 via a GLP-certified laboratory. The substance was determined to have an auto-ignition temperature of 370°C at 1012 - 1022 mbar.
Executive summary:

The substance was evaluated for auto flammability in accordance with EU Method A.15 via a GLP-certified laboratory.

A known mass of the substance was added to a heated open Erlenmeyer flask (200 mL) containing air. The contents of the flask were observed in a darkened room for five minutes following addition of a sample or until ignition occurred. Ignition was evidenced by the sudden appearance of a flame inside the flask. If a flame was not observed in five minutes, the amount of sample tested was considered non-flammable at the temperature of the test flask. If a flame was observed, the timer was stopped and the time interval between sample addition and the appearance of the flame recorded to the nearest second as the time-lag.

The test was repeated at different temperatures and with differing sample masses until the minimum ignition temperature was obtained at any mass. The temperature was reduced by 2°C and six replicate tests conducted using the amount at which the lowest ignition temperature was found.

The lowest flask temperature at which ignition occurred was taken as the auto-ignition temperature. The substance was determined to have an auto-ignition temperature of 370°C at 1012 - 1022 mbar.

Description of key information

The auto-ignition temperature was was evaluated in accordance with EU Method A.15 via a GLP-certified laboratory.

The test was repeated at different temperatures and with differing sample masses until the minimum ignition temperature was obtained at any mass. The temperature was reduced by 2°C and six replicate tests conducted using the amount at which the lowest ignition temperature was found. The lowest flask temperature at which ignition occurred was taken as the auto-ignition temperature.

The substance was determined to have an auto-ignition temperature of 370°C at 1012 - 1022 mbar.

Key value for chemical safety assessment

Additional information