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Physical & Chemical properties

Vapour pressure

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Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
12 Aug - 04 Oct 1999
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Qualifier:
according to guideline
Guideline:
EPA OPPTS 830.7950 (Vapor Pressure)
Qualifier:
according to guideline
Guideline:
other: Directive 94/37/EC, Annex I, Section 2, § 2.3
GLP compliance:
yes
Type of method:
gas saturation method
Temp.:
25 °C
Vapour pressure:
0 Pa
Remarks on result:
other: extrapolated

The trapping and extraction efficiency was checked with two different quantities.

Quantity / µg

First trap: recovery /%

Second trap: recovery /%

Total recovery /%

4.75

109.0

0.0

109.0

36.1

95.0

0.0

95.0

 

The preliminary tests showed that the substance vapours were completely collected by the first adsorption tube. The vapour pressures obtained at 50 °C were found 1.91E-6 and 1.60E-6 Pa when the gas flow rate was respectively 1 an 0.5 L/min. These results did not show a dependence on the flow rate.

Temperatur / K

324.8

315.5

Vapour pressure / Pa

1.6 E-6

6.3 E-7

The logarithm of the vapour pressure was found to be linear function of the inverse of the thermodynamic temperature according to the equation below.

Log P = (-5098 / T) + 8.05

The vapour pressure of the substance, calculated at 25 °C (298 K) was found to be 9.1E-8.

For the impurity profile of the test item recovered from the Raschig rings no significant changes were detected in the size or number of peaks observed. The quantification analysis by HPLC showed that the test item was stable under the operating conditions used for the experiment.

Description of key information

< 0.0001 Pa at 25 °C

Key value for chemical safety assessment

Vapour pressure:
0 Pa
at the temperature of:
25 °C

Additional information

The vapour pressure (9.1E-08 Pa at 25 °C) of the test item was determined according to OECD Guideline 104.