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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Description of first aid measures

Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). If not breathing, give artificial respiration. First aid personnel should pay attention to their own safety.

If inhaled:

Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.

On skin contact:

Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

On contact with eyes:

Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:

Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

Most important symptoms and effects, both acute and delayed

Symptoms: Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11., Further symptoms are possible

Indication of any immediate medical attention and special treatment needed

Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

Fire-Fighting Measures

Extinguishing media

Suitable extinguishing media:

dry powder, foam, water spray, carbon dioxide

Special hazards arising from the substance or mixture

Endangering substances: carbon monoxide, Carbon dioxide, nitrous gases

Advice for fire-fighters

Special protective equipment:

Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:

Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Accidental release measures

Accidental Release Measures

Personal precautions, protective equipment and emergency procedures

Breathing protection required. Avoid contact with the skin, eyes and clothing.

Environmental precautions

Do not discharge into drains/surface waters/groundwater.

Methods and material for containment and cleaning up

For large amounts: Pump off product.

For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).

Cleaning operations should be carried out only while wearing breathing apparatus. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.

Handling and storage

Precautions for safe handling

Ensure thorough ventilation of stores and work areas. Sealed containers should be protected against heat as this results in pressure build-up. Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.

Protection against fire and explosion:

Vapours may form explosive mixture with air. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Temperature class: T4 (Autoignition temperature >135 °C).

Conditions for safe storage, including any incompatibilities

Segregate from acids and acid forming substances.

Suitable materials for containers: Carbon steel (Iron), Stainless steel 1.4401, Stainless steel 1.4301 (V2), Stainless steel 1.4306 (V2A), enamelled, glass

Unsuitable materials for containers: Paper/Fibreboard

Further information on storage conditions: Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or flame.

Storage class according to TRGS 510 (originally VCI, Germany): (3) Flammable liquids

Storage stability:

Storage duration: 24 Months

From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

The packed product will not be damaged by high temperatures.

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

Control parameters

Components with occupational exposure limits

No occupational exposure limits known.

PNEC

freshwater: 0,0578 mg/l

marine water: 0,00578 mg/l

intermittent release: 0,0689 mg/l

STP: 73 mg/l

sediment (freshwater): 7,73 mg/kg

sediment (marine water): 0,773 mg/kg

soil: 1,51 mg/kg

oral (secondary poisoning):

No PNEC oral derived, as accumulation in organisms is not to be expected.

DNEL

worker:

Long-term exposure- systemic effects, Inhalation: 3,35 mg/m3

worker:

Long-term exposure - local effects, Inhalation: 3,49 mg/m3

worker:

Long-term exposure- systemic effects, dermal: 1,93 mg/kg

consumer:

Long-term exposure- systemic effects, oral: 0,9667 mg/kg

Exposure controls

Personal protective equipment

Respiratory protection:

Respiratory protection in case of vapour/aerosol release. Combination filter for gases/vapours of organic compounds and solid and liquid particles (f.e. EN 14387 Type A-P2) Combination filter for gases/vapours of organic, inorganic, acid inorganic and alkaline compounds (e.g. EN 14387 Type ABEK).

Suitable respiratory protection for higher concentrations or long-term effect: Self-contained breathing apparatus.

Hand protection:

Chemical resistant protective gloves (EN 374)

Suitable materials also with prolonged, direct contact (Recommended:  Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):

e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other

Manufacturer's directions for use should be observed because of great diversity of types.

Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:

Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Body protection:

chemical-protection suit (f.e. according to EN 14605)

General safety and hygiene measures

Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray. Take off immediately all contaminated clothing. Store work clothing separately.

Stability and reactivity

Reactivity

No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals:

Corrosive effects to metal are not anticipated. In the presence of water or moisture metal corrosion cannot be excluded.

Formation of flammable gases:       Remarks:       Forms no flammable gases in the presence of water.

Chemical stability

The product is stable if stored and handled as prescribed/indicated. The product may become unstable at elevated temperatures and under pressure.

Possibility of hazardous reactions

Strong exothermic reaction with acids.

Conditions to avoid

Avoid all sources of ignition: heat, sparks, open flame. See SDS section 7 - Handling and storage.

Incompatible materials

Substances to avoid:

acids, acid chlorides, acid anhydrides, Alkalines

hazardous decomposition products

Hazardous decomposition products:

carbon oxides, nitrogen oxides, nitrous gases

Disposal considerations

Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.

The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.

Contaminated packaging:

Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.